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TYROSYL HISTIDINE HCI.

Valuable CAS 94111-42-9 / ANTIOXIDANT

Tyrosyl Histidine HCl is a dipeptide crafted from L-tyrosine and L-histidine. Upon topical application, it is anticipated to cleave into these individual amino acids on the skin, primarily delivering L-histidine's multifaceted benefits for profound hydration, barrier integrity, and antioxidant protection.

Skin-Conditioning Agent Moisturizer Humectant Antioxidant pH Balancer Barrier Support UV Protectant

Science

This dipeptide serves as a precursor for L-histidine, which is subsequently released upon enzymatic cleavage within the skin. L-histidine functions as a potent humectant, effectively drawing and retaining moisture to significantly enhance skin hydration and reduce transepidermal water loss. It fortifies the skin barrier by potentially increasing levels of trans-urocanic acid (UCA), thereby restoring the optimal pH crucial for barrier maintenance and repair. Furthermore, L-histidine provides antioxidant defense, aids in collagen synthesis, helps regulate skin pH, diminishes inflammatory responses, and supports the skin's intrinsic repair and recovery mechanisms. Its conversion to trans-urocanate in the skin, followed by conversion to cis-urocanate upon UV exposure, may also offer protective properties.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 5 – 7
0 7 14

Stability

Tyrosine- and histidine-containing dipeptides are highly soluble in water and demonstrate general stability within a neutral pH range. Histidine, a key constituent, acts as an effective buffering agent, with optimal efficacy between pH 5.5 and 6.5, extending its buffering capacity to the pH range of 5.0-6.9 in formulations. The imidazole side chain of histidine has a pKa of approximately 6.0.

Conflicts

  • high concentrations with stainless steel at elevated temperatures
  • polysorbates (specifically in histidine buffer systems)

Safety

CIR Status
Not reviewed
Sensitization risk Unknown

A dedicated safety assessment for Tyrosyl Histidine HCl by the Cosmetic Ingredient Review (CIR) Expert Panel, Scientific Committee on Consumer Safety (SCCS), or FDA has not been identified. While its component, Histidine HCl, is listed in the CIR Portal Ingredient Status Report, specific details regarding its safety status were not ascertainable from the available information.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Tyrosyl Histidine HCl is a valuable ingredient, anticipated to enhance skin hydration, support barrier function, and offer antioxidant benefits through its L-histidine component, though specific clinical data on the dipeptide itself is limited.


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References