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SORBITAN OLEATE.

Valuable CAS 1338-43-8 / SURFACTANT - EMULSIFYING

Sorbitan Oleate is a versatile nonionic emulsifier and emollient, crucial for stabilizing formulations and enhancing skin hydration. It facilitates the harmonious blend of oil and water phases while contributing to a smoother, more moisturized skin feel.

Emulsifying Agent Emollient Surfactant Skin Conditioning Agent Active Ingredient Penetration Enhancer Pigment Dispersing Agent

Science

As a nonionic emulsifier, Sorbitan Oleate expertly stabilizes water-in-oil (W/O) emulsions and acts as a co-emulsifier for oil-in-water (O/W) systems, ensuring consistent product texture and stability. Beyond its structural role, it functions as an emollient, delivering non-greasy hydration to the skin, bolstering the natural barrier, and minimizing transepidermal water loss. Its surfactant properties aid in gentle cleansing, while evidence suggests it can improve the dermal penetration of other active ingredients and optimize pigment and mineral filter dispersion for enhanced product performance.


Research

Medium confidence
Effective range 0.5–10%
Optimal

N/A

Key findings

  1. 01 Clinical observations indicate use between 2% and 10% effectively dictates formulation richness, with lower concentrations yielding lighter textures and higher levels (up to 10%) creating thicker, more intensive products.
  2. 02 Typical cosmetic applications utilize concentrations from 0.5% to 5%, adaptable to specific formula stability and aesthetic requirements.
  3. 03 A specific study demonstrated that 1.435% Sorbitan Oleate, combined with 9.565% Polysorbate 80 in an optimized ethyl cinnamate foundation formulation, yielded a physically stable product with a pH of 6.478, viscosity of 5844.2 cPs, SPF of 22.385, and no reported irritation.

Transparency

Not commonly dusted
Min. effective
10%
Red flag below
10%

While generally well-tolerated, concentrations exceeding 10% are noted to potentially cause skin irritation, indicating a threshold for cautious formulation.


The Formula

Solubility
Oil
Optimal pH 6 – 7
0 7 14

Stability

As a lipophilic ingredient with an HLB value of 4.3, Sorbitan Oleate is highly soluble in ethanol, mineral oil, and vegetable oils, making it ideal for water-in-oil emulsions. Its very low water solubility necessitates its use in the oil phase. The ingredient demonstrates excellent thermal stability, resisting degradation up to approximately 200°C, and can be directly incorporated into formulations, streamlining manufacturing and preserving heat-sensitive components.

Synergies

  • High-HLB emulsifiers (for O/W emulsions)

Safety

CIR Status
Safe as used
Max tested
25%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has repeatedly affirmed Sorbitan Oleate's safety in cosmetics at current use concentrations, a stance supported by its Generally Recognized as Safe (GRAS) status from the FDA for food use. While generally considered mild, animal studies have indicated minimal to mild skin irritation, and concentrations above 10% may provoke irritation. It is important to note that some databases have flagged Sorbitan Oleate as a potential carcinogen based on in vitro cell mutation studies and liver effects in high-level animal tests; however, other studies indicate it is inactive as a tumor promoter and CIR's comprehensive reviews maintain its safety profile.


Your Skin

Yes Normal
Yes Dry
No Oily
Yes Sensitive
Irritancy Low
Comedogenicity Medium

Our Assessment

Valuable

Sorbitan Oleate is a valuable ingredient, effectively stabilizing emulsions and enhancing skin hydration, with a generally favorable safety profile when used within recommended concentrations.


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