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POLYGLYCERYL-4 STEARATE.

Valuable CAS 26855-44-7 / 37349-34-1 / 68004-11-5 / SURFACTANT - EMULSIFYING

Polyglyceryl-4 Stearate is a sophisticated, nonionic emulsifier derived from natural sources, expertly blending oil and water phases to create stable, uniform skincare formulations. Beyond its primary role in emulsion stabilization, it offers gentle conditioning benefits, contributing to a smooth and moisturized skin feel.

emulsifying skin conditioning

Science

This ingredient functions as a lipophilic surfactant, possessing a molecular architecture with distinct hydrophilic (polyglycerol) and lipophilic (stearic acid) segments. This duality enables it to significantly reduce the interfacial tension between immiscible oil and water phases, thereby facilitating the formation and long-term stability of emulsions. Within a cosmetic matrix, it ensures homogeneity and consistent product texture. Furthermore, it imparts moisturizing and softening properties, acting as a skin conditioning agent.


Research

Medium confidence
Effective range 1–5%
Optimal

N/A

Key findings

  1. 01 Typical usage concentrations for its emulsifying and stabilizing functions in formulations range from 1% to 5%.
  2. 02 Concentrations between 0.5% and 0.9% were observed to enhance emulsion stability, as indicated by lower stability index values in specific dairy cream emulsion studies.
  3. 03 An in vitro study confirmed a concentration of 0.5% to be non-cytotoxic for Polyglyceryl fatty acid ester (PGFE)-based nanostructured lipid carriers in Caco-2 cells, suggesting good cellular compatibility.

Transparency

Not commonly dusted

The available research data does not provide information regarding 'dusting' properties or concerns for Polyglyceryl-4 Stearate.


The Formula

Solubility
Both
Optimal pH 5 – 6
0 7 14

Stability

As a non-ionic emulsifier, Polyglyceryl-4 Stearate demonstrates robust stability across a wider pH range compared to its ionic counterparts, although extreme pH values can still influence overall formulation integrity. It exhibits good resistance to salts and acids, contributing to stable emulsions even under challenging conditions. Thermal stability is generally favorable, with Polyglycerol fatty acid esters (PGFEs) remaining stable under neutral conditions below 100°C.


Safety

CIR Status
Safe as used
Max tested
5%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has deemed polyglyceryl fatty acid esters, including Polyglyceryl-4 Stearate, safe for use in cosmetic products under current practices and concentrations, provided formulations are non-irritating. It is well-tolerated by most skin types and is an approved cosmetic ingredient within the European Union. Its absence from the FDA's Inactive Ingredient Database indicates it is not currently used as an excipient in approved US pharmaceutical products.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Polyglyceryl-4 Stearate is a valuable ingredient for its essential role in creating stable, elegant cosmetic emulsions and providing mild skin conditioning without concerns for irritancy or comedogenicity.


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References