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POLYGLYCERYL-20 HEXACAPRYLATE.

Valuable CAS - / SURFACTANT - CLEANSING

POLYGLYCERYL-20 HEXACAPRYLATE is a versatile polyglyceryl ester that functions as a highly effective surfactant, emulsifier, and solubilizer. It aids in blending immiscible phases and dissolving oil-loving ingredients into water-based formulations, while also providing skin conditioning benefits.

Surfactant Cleansing Emulsifying Solubilizer Skin-Conditioning

Science

This ingredient operates as a surfactant, actively reducing the surface tension of liquids to enable the fine mixing of typically immiscible substances, such as oil and water. It functions as a cleansing agent, an emulsifier to create stable product textures, and a solubilizer, facilitating the incorporation of lipophilic components into aqueous systems. As a polyglyceryl ester, it additionally contributes to skin conditioning, potentially forming subtle films that help normalize and hydrate the skin, and may enhance the transdermal penetration of other cosmetic actives.


Research

Medium confidence
Effective range 2.5–10%
Optimal

N/A

Key findings

  1. 01 A related polyglyceryl caprylate, Polyglyceryl-10 monocaprylate, demonstrated the ability to self-assemble into transparent nanoparticles within an effective concentration range of 2.5-10 wt%. This showed good makeup removal efficacy, particularly against challenging pen eyeliner.
  2. 02 In a broader assessment, polyglycerol esters (PGEs), the category encompassing POLYGLYCERYL-20 HEXACAPRYLATE, did not induce adverse effects when tested at a 5 wt% concentration.

Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH 5.5 – 10
0 7 14

Stability

Polyglycerol fatty acid esters generally exhibit thermal stability below 100 °C under neutral conditions. However, the ester linkage is susceptible to accelerated hydrolysis in acidic or basic environments, and can also be degraded by lipases. The suggested optimal pH range of 5.5-10.0 is derived from studies on related polyglyceryl esters, indicating general stability within these parameters.


Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has affirmed the safety of POLYGLYCERYL-20 HEXACAPRYLATE, along with 273 other polyglyceryl fatty acid esters, in current cosmetic practices and concentrations, provided they are formulated to be non-irritating and non-sensitizing. These esters are recognized for being biodegradable, biocompatible, noncarcinogenic, and non-toxic. They are considered a 'green' alternative to PEG-based surfactants, as they avoid the risk of 1,4-dioxane contamination typically above the SCCS-recommended limit of 10 ppm. While not explicitly stated for cosmetic use by the FDA, polyglycerol esters are approved food additives.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

POLYGLYCERYL-20 HEXACAPRYLATE is a valuable, safe, and versatile ingredient, functioning as an effective surfactant, emulsifier, and solubilizer with broad skin compatibility and low irritation potential across diverse cosmetic applications.


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