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PEG-45M.

Valuable CAS 25322-68-3 / HUMECTANT

PEG-45M is a high molecular weight polyethylene glycol polymer, valued in skincare for its multi-functional properties. It enhances skin hydration and smoothness, forming a protective film to minimize moisture loss, while also improving product texture and stability.

Viscosity controlling Binder Film-forming Humectant Emollient Emulsion Stabilizer Solubilizer

Science

On the skin, PEG-45M functions as a humectant by forming hydrogen bonds with water molecules, thereby attracting and retaining moisture for sustained hydration and preventing dryness. It also acts as an emollient, delivering a smooth and soft skin feel. Furthermore, its film-forming capabilities create a uniform barrier that reduces transepidermal water loss and aids the adherence and even distribution of other conditioning agents. In formulations, it serves as a thickener, viscosity-increasing agent, and emulsion stabilizer, while also improving rheological properties and solubilizing poorly soluble substances.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

PEG-45M is a stable white powder with a light odor, resisting decomposition, heat, acids, and alkalis. It dissolves effectively in water with heat (around 80°C) or more readily in glycol components (70-80°C) if present in the formulation.

Synergies

  • Cetyl Alcohol
  • Glycerin
  • Propylene Glycol
  • Butylene Glycol

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has affirmed PEG-45M's safety for use in cosmetic applications. This high molecular weight PEG (45,000 units) is not absorbed through healthy, intact skin and exhibits very low oral and dermal toxicity, with no mutagenic or carcinogenic properties. While manufacturing processes address potential 1,4-dioxane contamination, caution is advised for compromised or severely damaged skin, where increased penetration could lead to irritation. Allergic reactions are uncommon topically, but a patch test is prudent for individuals with heightened sensitivity.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

PEG-45M is a valuable, safe, and versatile polymer that enhances skin hydration and texture while contributing to product stability and sensorial experience.


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