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PEG-4 ETHYLHEXANOATE.

Valuable / SURFACTANT - EMULSIFYING

PEG-4 Ethylhexanoate is a versatile synthetic ester that functions as a skin conditioning agent, helping to soften and hydrate the skin. It contributes to formulation stability by emulsifying oil and water components and serves as a solvent for other active ingredients.

emollient humectant solvent emulsifier skin conditioning

Science

This ingredient operates primarily as an emollient, promoting a softer and smoother skin texture, and as a humectant, effectively drawing and retaining moisture to enhance epidermal hydration. Its amphiphilic nature enables it to act as an effective emulsifier, facilitating the stable integration of immiscible oil and water phases within cosmetic formulations. Additionally, it functions as a solvent, aiding in the dissolution of other compounds, and possesses the capability to enhance the penetration of co-formulated active ingredients into the skin.


Research

Insufficient-data confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH 4 – 9
0 7 14

Stability

PEG-4 Ethylhexanoate demonstrates robust stability across a wide pH range of 4.0 to 9.0, with no significant hydrolysis anticipated within this spectrum. It exhibits high solubility in both aqueous solutions and various organic solvents, and its amphiphilic structure allows for excellent dispersibility in water-based formulations.


Safety

CIR Status
Safe as used
Max tested
2.5%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has affirmed the safety of PEG ingredients, including PEG-4, for use in cosmetic products. It is characterized by low toxicity and a minimal propensity for causing skin irritation or sensitization. While concentrations up to 20% have been reported for PEG-4 in specialized applications such as manicure preparations, a general maximum concentration of ≤ 2.5% is typically considered safe for cosmetic use, often referenced in conjunction with related PEG esters like PEG-5 Ethylhexanoate. A critical safety consideration involves potential impurities such as 1,4-dioxane and ethylene oxide, which are by-products of the manufacturing process; however, reputable ingredient suppliers rigorously control these levels to ensure consumer safety. As a penetration enhancer, PEG-4 Ethylhexanoate may augment the absorption of other active components in a formulation. In exceedingly rare instances, PEGs have been implicated in anaphylaxis or hypersensitivity reactions.


Your Skin

Yes Normal
Yes Dry
No Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

PEG-4 Ethylhexanoate is a valuable ingredient for its multifunctional role in enhancing skin hydration and texture while supporting stable cosmetic formulations and potentially boosting ingredient delivery, with a favorable safety profile.


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