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OCTOXYNOL-33.

Valuable CAS 9002-93-1 / CLEANSING, SURFACTANT - CLEANSING, SURFACTANT - EMULSIFYING

Octoxynol-33 is a long-chain non-ionic surfactant primarily utilized in skincare formulations for its emulsifying, cleansing, and solubilizing properties. It effectively reduces surface tension, enabling the harmonious blend of immiscible liquids like oil and water, and assists in the dissolution of challenging ingredients within a formula.

emulsifying surfactant cleansing solubilizing hydrotrope

Science

As a surfactant, Octoxynol-33 functions by lowering the surface tension between different phases, facilitating the formation of stable emulsions. This action is crucial for dispersing oil and dirt in water, allowing for effective rinsing in cleansing products. Additionally, its longer-chain structure endows it with hydrotropic capabilities, enhancing the solubility of other compounds that typically resist dissolution in a given solvent.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

No specific optimal pH range for the stability of Octoxynol-33 has been identified in the provided research. Given its synthesis under elevated temperature, pressure, and with NaOH, formulators should focus on minimizing impurities such as heavy metals and ethylene oxide in final cosmetic products, adhering strictly to established regulatory limits for product integrity and safety.


Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded that long-chain octoxynols, including Octoxynol-33, are safe for use in both rinse-off and leave-on cosmetic formulations when precisely formulated to be non-irritating. This determination was re-affirmed in an amended report issued in March 2025. It is important to note that while the FDA has approved Octoxynol-33 for indirect food contact applications, its use in Europe is subject to authorization, as octoxynols are classified as 'substances of very high concern' due to documented toxicity to aquatic life with long-lasting environmental effects.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Octoxynol-33 is a valuable functional ingredient for cosmetic formulation, serving effectively as a surfactant and solubilizer, with its safety profile affirmed by CIR for cosmetic use when formulated to be non-irritating, despite specific environmental concerns in European regulations.


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References