Get a Free 5ml Mini Now Free 5ml Mini With Every Order of The Mantle

NIACIN.

Essential CAS 59-67-6 / ANTISTATIC, SMOOTHING

Niacin, specifically in its amide form, Niacinamide (Nicotinamide), is a versatile B vitamin known for its comprehensive benefits across various skin concerns. It plays a pivotal role in cellular health, visibly improving skin texture, tone, and overall resilience. This ingredient is well-tolerated and suitable for a wide range of skin types.

Anti-aging Wrinkle-smoothing Collagen boosting Improves skin structure Fades hyperpigmentation (brown spots) Reduces excess oil (sebum) Reduces blemishes Reduces redness Provides hydration Improves skin texture Pore minimization Supports skin barrier function Antioxidant

Science

Niacinamide functions as a precursor to vital coenzymes NAD and NADP, essential for cellular energy, metabolism, and lipid synthesis, helping to counteract age-related depletion. It supports skin barrier function by stimulating the production of ceramides and other lipids in the stratum corneum, significantly reducing trans-epidermal water loss. Its anti-inflammatory properties modulate pro-inflammatory cytokines, making it beneficial for redness and irritation. Furthermore, Niacinamide acts as an antioxidant by scavenging reactive oxygen species, regulates sebum production, and addresses hyperpigmentation by disrupting melanosome transfer to keratinocytes. It also promotes collagen synthesis, inhibits protein glycation, and reduces excessive glycosaminoglycan deposition, contributing to anti-aging effects.


Research

High confidence
Effective range 1–10%
Optimal

5%

Key findings

  1. 01 Demonstrated a 21.8% reduction in actinic keratoses over three months compared to a control.
  2. 02 Achieved significant reductions in sebum excretion rate and pore size within four weeks, alongside improved skin hydration and texture.
  3. 03 Led to reduced pores and improved skin unevenness after 8 weeks, with wrinkle improvement observed after 12 weeks.
  4. 04 Effective for general skin tone correction, demonstrating improvements in fine lines, wrinkles, hyperpigmented spots, skin texture, red blotchiness, and sallowness over a 12-week period.
  5. 05 Beneficial for more pronounced hyperpigmentation, with clinical tests indicating no stinging sensation at this concentration.

Transparency

Not commonly dusted
Min. effective
1%

Niacinamide shows demonstrable benefits even at concentrations as low as 1% for specific concerns like actinic keratoses. General cosmetic benefits for sebum and pore size are evident from 2%, and a wide array of anti-aging and tone correction benefits are seen at 4-5%. Therefore, its inclusion at lower percentages is not considered 'dusting' as it still provides measurable efficacy, with higher concentrations addressing more pronounced issues.


The Formula

Solubility
Water
Optimal pH 5 – 7
0 7 14

Stability

Niacinamide is a highly stable vitamin, with optimal stability and penetration observed in formulations with a pH between 6.0 and 7.0. While stable within a broader pH range (3.0 to 7.5), highly acidic conditions (below pH 5) may lead to its hydrolysis into nicotinic acid, potentially causing temporary skin redness or flushing. However, this conversion typically requires extreme conditions rarely encountered in well-formulated cosmetic products.

Conflicts

  • High concentrations (e.g., above 5-10%), especially when layered with multiple products, may induce irritation or a histamine response in sensitive individuals.
  • Strongly acidic environments (below pH 5) can promote conversion to nicotinic acid, potentially causing skin flushing and irritation.
  • Historically, combining with L-ascorbic acid (Vitamin C) was cautioned due to concerns of inactivation; however, modern formulation advancements allow for effective co-formulation with appropriate pH control. For highly sensitive skin, separate application times (e.g., AM/PM) or allowing time between applications may still be recommended.
  • Pairing with strong exfoliating acids (AHAs/BHAs like glycolic or salicylic acid) can occasionally increase irritation, particularly for sensitive skin, due to differing optimal pH requirements. It is often advisable to use these ingredients on alternating days or select products specifically designed for combined use.

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel concluded Niacinamide and Niacin are toxicologically similar and safe for cosmetic use, with no restrictions on maximum concentration by the EU. Clinical testing indicates no significant skin irritation, sensitization, or photosensitization. Use tests reported no irritation up to 5% and no stinging sensation up to 10% concentrations. Niacinamide is also recognized as generally safe (GRAS) as a nutrient supplement by the FDA and is approved in prescription products for pellagra treatment.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Essential

Niacinamide is an essential ingredient due to its exceptional versatility, broad range of clinically proven benefits from 1-10%, excellent safety profile, and compatibility across all skin types, making it a cornerstone for comprehensive skin health and improvement.


Related

Finding similar ingredients…


References