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MANNITOL.

Valuable CAS 69-65-8 / BINDING, FRAGRANCE, HUMECTANT, MOISTURISING, SKIN CONDITIONING

Mannitol is a sugar alcohol known for its humectant properties, drawing moisture into the skin to enhance hydration and smoothness. It also offers antioxidant benefits, helping to shield the skin from environmental stressors and oxidative damage, contributing to a healthy complexion.

humectant antioxidant skin conditioning masking binding moisturising

Science

Mannitol primarily acts as a humectant, efficiently attracting and retaining water within the skin's surface layers to prevent dehydration and maintain suppleness. Beyond hydration, it functions as an antioxidant, neutralizing free radicals generated by UV exposure and pollution, thus protecting against premature aging. Additionally, it helps to condition the skin and can improve product texture and stability by acting as a binding or viscosity control agent.


Research

Low confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 When co-administered via a "depot" injection with 13.5 mg/g uncross-linked hyaluronic acid, a 0.9% concentration of Mannitol significantly improved skin hydration, anisotropy, and roughness. A separate study indicated Mannitol alone had no irritating effect on the skin.

Transparency

Not commonly dusted

No data suggests Mannitol is commonly used at ineffective 'dusted' concentrations. Its reported maximum concentration in leave-on products is high, indicating its utility at significant levels.


The Formula

Solubility
Water
Optimal pH 5 – 6.5
0 7 14

Stability

Mannitol is readily soluble in water, with an optimal pH range for formulation typically between 5.0 and 6.5. In aqueous solutions, it can become slightly acidic due to hydrogen ion loss, often requiring pH adjustment. Solutions greater than 10% w/v may experience recrystallization, particularly below 21°C, though diluted solutions with a final concentration less than 15% are less prone to this.

Synergies

  • Hyaluronic Acid (for enhanced skin hydration and elasticity in injected applications)

Safety

CIR Status
Safe as used
Max tested
60.5%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel concluded Mannitol is safe for cosmetic use within current practices and concentrations, with a highest reported leave-on dermal exposure at 60.5%. It is also FDA-approved as a Generally Recognized As Safe (GRAS) direct food additive. Mannitol is considered non-toxic, non-irritating, and non-comedogenic, without specific usage restrictions.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Mannitol is a valuable polyol offering versatile humectant and antioxidant benefits, suitable for all skin types due to its excellent safety and compatibility profile.


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