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IRON HYDROXIDE.

Valuable CAS 20344-49-4 / LIGHT STABILIZER

Iron Hydroxide, predominantly known as Yellow Iron Oxide (CI 77492) in cosmetics, functions as a highly stable pigment. Beyond its coloring properties, this compound forms a protective physical barrier on the skin, significantly contributing to blue light attenuation and preventing hyperpigmentation.

Colorant UV Filter Blue Light Filter

Science

As a physical barrier, Iron Hydroxide, specifically Yellow Iron Oxide (CI 77492), operates by physically reflecting and scattering High Energy Visible (HEV) blue light upon skin contact. This action effectively reduces blue light's impact on melanocytes, consequently inhibiting excessive melanin synthesis responsible for dark spots and conditions like melasma. Furthermore, studies suggest that certain iron oxide nanoparticles may impart antioxidant protection by mitigating oxidative stress.


Research

Medium confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The provided research data does not contain information regarding dusting properties or thresholds for Iron Hydroxide in cosmetic applications.


The Formula

Solubility
Unknown
Optimal pH 3 – 11
0 7 14

Stability

Iron Hydroxide (as iron oxides) demonstrates robust chemical stability, resisting degradation from light, heat, or chemical exposure, which ensures consistent color. It maintains excellent pH stability across a broad range of 3 to 11. However, Yellow Iron Oxides are sensitive to high temperatures (125-150°C), at which they can visibly shift color due to the loss of water of hydration. As a magnetic compound, careful selection of production vessels is necessary to prevent coating of iron or mild steel. Cosmetic-grade iron oxides must adhere to strict limits on water-soluble salts and organic matter to maintain product stability.


Safety

CIR Status
Deferred evaluation | covered by FDA
Sensitization risk Low

The safety of iron oxides, including Iron Hydroxide, has been assessed by the U.S. Food and Drug Administration (FDA), which lists them as color additives exempt from certification and safe for use in cosmetics, including products applied to the lips and eye area, provided they meet specific purity requirements for heavy metal contamination. Yellow Iron Oxide (CI 77492), corresponding to iron (III) hydroxide (FeO(OH)·H2O), is described as practically nontoxic, non-irritating to skin and mucous membranes, and non-allergenic, with low dermal absorption. The EWG Skin Deep database assigns Iron Hydroxide (Fe(OH)2) a low hazard score across categories including cancer, allergies & immunotoxicity, and developmental toxicity. SkinSAFE further lists it as 'Teen SAFE', 'Lip SAFE', 'Baby SAFE', 'Eyelid SAFE', and 'Irritant Free'.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Iron Hydroxide is a valuable ingredient, prized for its excellent safety profile, broad skin compatibility, and critical function in providing blue light protection, which is highly beneficial for preventing and managing hyperpigmentation.


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