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CAFFEOYL PENTAPEPTIDE-4.

Valuable / SKIN CONDITIONING

A high-performance conjugated matrikine that bridges the gap between potent antioxidant protection and structural dermal repair. By fusing caffeic acid with a signaling peptide, this molecule offers a targeted approach to age management without the inflammatory profile associated with traditional retinoids.

Dermal remodeling Collagen synthesis stimulation Antioxidant protection MMP-1 inhibition

Science

This ingredient functions as a cellular messenger (KTTKS sequence) that instructs fibroblasts to synthesize essential structural components including Type I, III, and IV collagen and glycosaminoglycans. Simultaneously, its caffeoyl moiety acts as a biological shield, neutralising UV-induced oxidative stress and inhibiting Matrix Metalloproteinase-1 (MMP-1), the enzyme responsible for collagen degradation.


Research

High confidence
Effective range 0.0003–0.012%
Optimal

0.0003%

Key findings

  1. 01 Comparative trials indicate that a 3 ppm (0.0003%) concentration delivers anti-wrinkle efficacy comparable to 0.07% retinol but with significantly improved skin tolerability.
  2. 02 In vitro studies on human skin fibroblasts at 10-50 µM concentrations demonstrated a marked increase in Type I collagen production and a decrease in collagen-thinning enzymes.

Transparency

Commonly dusted
Min. effective
0.0001%
Red flag below
0.00005%

Because this peptide is biologically active at incredibly low parts-per-million (ppm), many brands include it at 'trace' levels for label claims without reaching the 3 ppm threshold required to match retinol-like performance.


The Formula

Solubility
Water
Optimal pH 4.5 – 6.5
0 7 14

Stability

The caffeoyl conjugation enhances the peptide's oxidative stability, though the molecule remains sensitive to extreme pH levels which can trigger hydrolysis.

Synergies

  • Hyaluronic Acid
  • Niacinamide
  • Other signaling peptides
  • Non-acidic antioxidants

Conflicts

  • Strong Alpha Hydroxy Acids (Low pH)
  • L-Ascorbic Acid
  • Proteolytic enzymes
  • Strong oxidizing agents

Safety

CIR Status
Safe as used
Max tested
0.012%
Pregnancy
Safe
Sensitization risk Low

While the caffeoyl derivative is modern, its parent peptide (Pentapeptide-4) has been thoroughly vetted by the CIR as safe for leave-on cosmetic use.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An elite signaling peptide for sensitive skin types seeking retinol-level results in collagen density and wrinkle reduction without the irritation.


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References