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BENZOIC ACID/PHTHALIC ANHYDRIDE/PENTAERYTHRITOL/NEOPENTYL GLYCOL/PALMITIC ACID COPOLYMER.

Valuable CAS 68647-39-2 / FILM FORMING

A sophisticated multi-monomer polyester designed to provide a high-performance protective barrier on the skin and hair. This copolymer balances structural rigidity with lipid-rich flexibility to ensure long-wearing, water-resistant coverage in advanced cosmetic formulations.

Film forming Texture enhancer Waterproofing agent

Science

The copolymer functions by creating a hydrophobic, continuous microfilm across the application surface. It utilizes a molecular architecture that combines rigid aromatic units for durability with branched, flexible glycols and fatty acids for elasticity, allowing it to adhere to keratinous structures without cracking or peeling while sealing in moisture and active ingredients.


Research

Medium confidence
Effective range 0.1–15%
Optimal

5%

Key findings

  1. 01 Demonstrated utility in durable hair and nail compositions, creating a flexible and moisture-resistant film at concentrations up to 15%.

Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.05%

As a functional film-former, it is rarely 'dusted' because its physical effects on product texture and wear-time are detectable at very low thresholds; however, significant water-resistance benefits typically require concentrations above 1%.


The Formula

Solubility
Oil
Optimal pH 4 – 8
0 7 14

Stability

Maintains structural integrity within standard cosmetic pH ranges but may undergo hydrolysis if exposed to highly acidic (pH <3) or strongly alkaline (pH >9) environments.

Synergies

  • Lipophilic sunscreens
  • Mineral pigments
  • Hydrophobic emollients

Conflicts

  • Strongly alkaline ingredients
  • Strong oxidizing agents
  • Highly acidic systems

Safety

CIR Status
Not reviewed
Max tested
32.8%
Pregnancy
Safe
Sensitization risk Low

While not individually assessed by the CIR, it belongs to a class of anhydride copolymers deemed safe for use in nail and cosmetic products up to 32.8%.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

An excellent auxiliary ingredient for enhancing the durability and water-resistance of protective skincare and color cosmetics.


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