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4-NITRO-O-PHENYLENEDIAMINE DIHYDROCHLORIDE.

Avoid CAS 6219-77-8 / HAIR DYEING

A substituted aromatic amine compound primarily utilized as a chromogen in oxidative hair coloring formulations. This water-soluble dye precursor penetrates the hair shaft and reacts under oxidative conditions to form larger pigment molecules, typically producing red, brown, or blonde color tones.

hair dyeing

Science

Functions as a dye precursor that penetrates hair fibers and undergoes oxidative coupling reactions with other precursors to form permanent color molecules within the hair structure


Research

High confidence
Effective range 0.049–0.5%
Optimal

0.049%

Key findings

  1. 01 Repeated insult patch testing on 206 volunteers at 0.049% showed no irritation or sensitization reactions
  2. 02 Guinea pig studies at 3% demonstrated significant sensitization potential (90% reaction rate)
  3. 03 Rabbit studies showed concentration-dependent irritation: non-irritating at 2.5%, slight irritation at 5%

Transparency

Not commonly dusted
Red flag below
0.5%

Restricted ingredient with specific regulatory limits; not applicable for general skincare formulations


The Formula

Solubility
Water
Optimal pH 5 – 7
0 7 14

Stability

Dihydrochloride salt form enhances water solubility compared to base compound. Requires protection from heat, light, and moisture due to oxidation sensitivity. Best incorporated into shampoo-based systems or oxidative dye creams.

Conflicts

  • Strong oxidizing agents (except controlled hair dye reactions)
  • Strong acids
  • Heavy metal ions

Safety

CIR Status
Safe with restrictions
Max tested
0.5%
Sensitization risk High

CIR and SCCS approve use only in oxidative hair dyes up to 0.5% on-head concentration. Recognized as potential human sensitizer. Prohibited in general skincare applications and restricted under EU Annex III.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Avoid

Restricted hair dye ingredient with significant sensitization potential that is inappropriate for precision skincare formulations.


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