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2,6-DIMETHYL-P-PHENYLENEDIAMINE HCL.

Avoid CAS 56496-89-0 / HAIR DYEING

An oxidative hair dye precursor compound that forms permanent color pigments through oxidation reactions within the hair shaft. This ingredient is specifically restricted to hair coloring applications due to its potent sensitizing properties and is unsuitable for skin-contact formulations.

hair dyeing

Science

Functions as a chemical intermediate that penetrates hair fibers and reacts with oxidizing agents like hydrogen peroxide to create large, stable color molecules trapped within the hair structure. Upon skin contact, acts as a hapten by binding to skin proteins, potentially triggering delayed-type hypersensitivity reactions.


Research

High confidence
Effective range 1–6%
Optimal

2%

Key findings

  1. 01 CIR Expert Panel determined safety for hair dye applications up to 6% concentration in non-sensitized individuals, with typical diluted on-scalp concentrations limited to 1-2%

Transparency

Not commonly dusted

Not applicable for skincare formulations due to safety restrictions limiting use to hair products only


The Formula

Solubility
Water
Optimal pH 2.7 – 7
0 7 14

Stability

Exhibits significant instability when exposed to light and atmospheric oxygen, leading to rapid darkening through oxidation. Hydrochloride salt form enhances water solubility and maintains stability in acidic to neutral pH environments prior to developer activation.

Conflicts

  • Oxidizing agents
  • Strong bases
  • Iron (III) chloride
  • Air (oxygen)
  • Light

Safety

CIR Status
Safe with restrictions
Max tested
6%
Sensitization risk High

Approved exclusively for permanent hair dye formulations. Prohibited in products intended for skin, eyelash, or eyebrow contact due to strong sensitization potential.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Restricted to hair applications only due to high sensitization risk, making it unsuitable for precision skincare formulations.


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