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TRIMETHYLOLPROPANE TRIACRYLATE.

Avoid CAS 15625-89-5 / FILM FORMING, HAIR CONDITIONING, HAIR FIXING

Trimethylolpropane Triacrylate (TMPTA) is a trifunctional acrylate ester monomer historically recognized for its film-forming and hair conditioning properties. However, due to its classification as a probable human carcinogen and a strong irritant, its use in cosmetics is strictly prohibited.

Science

While historically utilized to create a continuous film on skin, hair, or nails and impart conditioning benefits, chemically, TMPTA is a highly reactive monomer. It participates in free radical polymerization, functioning primarily as a cross-linking agent and reactive diluent to enhance properties like hardness and chemical resistance in industrial polymer coatings.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted
Min. effective
0.1%
Red flag below
0.1%

Trimethylolpropane Triacrylate is prohibited for use in cosmetics under the EU Cosmetics Regulation. The European Chemicals Agency (ECHA) mandates specific carcinogen labeling for formulations containing more than 0.1% of the substance, highlighting a critical safety threshold for non-cosmetic applications. Its presence at any level in a skincare formulation raises significant safety concerns due to its regulatory status as a carcinogen and irritant.


The Formula

Solubility
Both
Optimal pH N/A
0 7 14

Stability

TMPTA is practically stable in water, showing resistance to hydrolysis, and is soluble in various organic solvents. However, it is highly prone to spontaneous polymerization upon exposure to light and strong heat. It is also incompatible with strong oxidizing agents, acids, and bases, necessitating careful handling and storage.

Conflicts

  • strong oxidizing agents
  • strong acids
  • strong bases
  • brass
  • copper
  • steel (all types and surface treatments)
  • iron
  • iron salts
  • light
  • heat

Safety

CIR Status
Not reviewed
Sensitization risk High

Trimethylolpropane Triacrylate has been classified as a Group 2B substance (possibly carcinogenic to humans) by the International Agency for Research on Cancer (IARC). California's Proposition 65 lists it as a carcinogen, effective from late 2022. The European Chemicals Agency (ECHA) classified TMPTA as a Class 2 carcinogen from late 2023. It is also documented to cause skin irritation, serious eye irritation, and has the potential to cause an allergic skin reaction. Consequently, the use of Trimethylolpropane Triacrylate in cosmetics is entirely prohibited by the EU Cosmetics Regulation.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Trimethylolpropane Triacrylate is a probable human carcinogen, a potent irritant, and its application in cosmetic products is explicitly prohibited by EU regulations, rendering it unsuitable for any precision skincare formulation.


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