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TRIMETHYLHEXANAL.

Avoid CAS 5435-64-3 / PERFUMING

Trimethylhexanal is a synthetic aldehyde primarily utilized in cosmetic formulations for its fresh, citrus-like, and green aromatic notes, alongside its capability to mask undesirable odors. It offers no identified direct therapeutic benefits for skin health.

Fragrance Masking

Science

This compound primarily functions by imparting a distinct olfactive character to cosmetic products, acting as a fragrance component. Additionally, it serves as a masking agent, effectively neutralizing or concealing other undesirable scents within formulations. No inherent beneficial skin mechanism, such as antioxidant or moisturizing properties, has been identified.


Research

Insufficient-data confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH N/A
0 7 14

Stability

As a branched aldehyde, Trimethylhexanal demonstrates relative stability against oxidation and polymerization. However, its inherent reactivity necessitates stringent control, particularly exclusion of oxygen, during storage and processing. It exhibits low water solubility (approximately 0.01% or 100 mg/L at 20°C) but is readily soluble in alcohol.

Conflicts

  • Anthranilates (forms intensely yellow condensation products)
  • Quinolines (forms darker condensation products)
  • Indoles (forms darker condensation products)
  • Strong oxidizing agents
  • Strong bases

Safety

CIR Status
Not reviewed
Sensitization risk High

A 2022 RIFM safety assessment concluded Trimethylhexanal is not genotoxic and provided a calculated Margin of Exposure (MOE) exceeding 100 for repeated dose toxicity. However, it is unequivocally identified as a skin sensitizer, with a No Expected Sensitization Induction Level (NESIL) of 2900 μg/cm². Maximum acceptable concentrations, guided by IFRA standards, are product-category dependent, e.g., 0.22% for lip products, 0.066% for axillary products, and 0.89% for face/body products applied by fingertips. The FDA and JECFA classify it as a safe flavoring agent at current intake levels. PubChem also explicitly notes that it 'Causes skin irritation' (H315) and 'May cause an allergic skin reaction' (H317).


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

As a confirmed skin sensitizer and irritant with no identified therapeutic benefits for skin, Trimethylhexanal is not recommended for precision skincare formulations.


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References