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STYRENE/ACRYLATES/ACRYLONITRILE COPOLYMER.

Valuable / FILM FORMING, OPACIFYING, VISCOSITY CONTROLLING

Styrene/Acrylates/Acrylonitrile Copolymer is a sophisticated polymeric ingredient primarily valued for its film-forming properties, creating a breathable yet protective barrier on the skin. It significantly enhances product aesthetics and stability while contributing to improved skin hydration and defense against environmental factors.

Film-forming Opacifying Viscosity-controlling SPF boosting Water-resistant agent Protective barrier Moisture retention Texture enhancer Formulation stabilizer

Science

This copolymer operates by forming a pliable, continuous, and cohesive film upon application, which physically remains on the skin's surface due to its substantial molecular weight, thus preventing percutaneous absorption. This formed film acts as a protective barrier, effectively minimizing transepidermal water loss to lock in moisture and shield the skin from external stressors. In sunscreens, its film-forming action contributes substantially to water resistance and can enhance SPF values. Beyond direct skin benefits, it functions as an opacifying and viscosity-controlling agent, optimizing product texture for smoother application and stabilizing formulations by preventing ingredient separation.


Research

Low confidence
Effective range N/A
Optimal

1%

Key findings

  1. 01 A clinical observation indicated that at a 1% concentration, a related Styrene/Acrylates Copolymer improved the SPF value of sunscreen formulations by approximately 11-18%.

Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH ≥6
0 7 14

Stability

The copolymer demonstrates stability under recommended storage conditions. For optimal mechanical stability in aqueous dispersions of similar copolymers, adjusting the final mixture to a pH greater than 6 is beneficial. While inherently hydrophobic with low water solubility, it is frequently utilized in water-based emulsion systems. The incorporation of styrene into styrene-acrylic copolymers can influence the film's water absorption and flexibility.

Conflicts

  • strong oxidizing agents

Safety

CIR Status
Safe as used
Max tested
35%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel concluded that styrene and vinyl-type styrene copolymers, including this ingredient, are safe within current cosmetic use practices and concentrations. This assessment is based on their large molecular size, which prevents percutaneous absorption, and consistent negative toxicity tests. Safety is further contingent on proper formulation to ensure the product is non-irritating. A maximum reported use concentration for Styrene/Acrylates Copolymer (a related ingredient) was 35%. While there is a recognized concern regarding potential residual styrene monomer, which is a possible carcinogen, stringent manufacturing processes ensure these levels are minimized in compliant cosmetic grades. It is crucial to distinguish that the SCCS identified insufficient data to conclude on the safety of *nano* forms (e.g., at 0.06% in leave-on products), a specific concern not generally applicable to its non-nano counterpart. Furthermore, Styrene-Acrylonitrile (SAN) copolymers have received FDA approval for direct food contact applications, indicating a favorable general safety profile for this polymer class.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Styrene/Acrylates/Acrylonitrile Copolymer is a valuable multi-functional ingredient, enhancing product performance through effective film-formation and stabilization while providing notable benefits for skin protection and hydration across all skin types.


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