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SODIUM THIOGLYCOLATE.

Questionable CAS 367-51-1 / ANTIOXIDANT, DEPILATORY, HAIR WAVING OR STRAIGHTENING, REDUCING

Sodium Thioglycolate is a powerful reducing agent primarily recognized for its role in altering hair structure through the breaking of disulfide bonds. It also functions as an antioxidant, scavenging free radicals in cosmetic formulations.

reducing depilatory antioxidant hair fixative exfoliating nail softening

Science

This ingredient functions as a reducing agent, specifically targeting the disulfide bonds found in keratin, the primary protein in hair. By breaking these bonds, it allows hair to be reshaped (for perms or straightening) or chemically dissolved for removal (depilation). On the skin, its reducing properties can also contribute to exfoliation, and it exhibits antioxidant activity by neutralizing free radicals.


Research

High confidence
Effective range ≤5%
Optimal

5%

Key findings

  1. 01 Concentrations up to 5.0% (as Thioglycolic Acid) are considered safe for depilatories when formulated to be non-irritating.
  2. 02 Reported concentrations in depilatories include 4% (NTP Technical Report).

Transparency

Not commonly dusted

Sodium Thioglycolate is not typically 'dusted' or used in low, broad-application percentages. Its efficacy relies on specific concentrations for targeted actions like depilation or hair treatment, which carry significant safety considerations if not properly formulated and used.


The Formula

Solubility
Water
Optimal pH 6.5 – 8
0 7 14

Stability

Sodium Thioglycolate is hygroscopic and oxidizes upon exposure to air, forming dithiodiglycolic acid; this oxidation rate increases with higher pH and dilution, leading to discoloration (yellowing). It is also incompatible with iron and other metals. For optimal stability, it should be stored in tightly closed, dry, well-ventilated, locked containers under inert gas, protected from light, and ideally at -20 °C, avoiding metal contact.

Conflicts

  • metals
  • air
  • iron
  • moisture

Safety

CIR Status
Safe with restrictions
Max tested
15.2%
Sensitization risk High

The Cosmetic Ingredient Review (CIR) Expert Panel deemed Sodium Thioglycolate safe for use in various hair products up to 15.2% (as Thioglycolic Acid), and in depilatories up to 5.0% (as Thioglycolic Acid) when formulated to be non-irritating. However, it is a contact irritant and corrosive substance, capable of causing severe skin burns and eye damage. Hairdressers must avoid skin contact, and consumer exposure should be minimized. While direct sensitization data for sodium thioglycolate is limited, its structural analogue, ammonium thioglycolate, is a known sensitizer.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Questionable

While effective as a depilatory and hair restructuring agent at specific concentrations, Sodium Thioglycolate's high irritancy and corrosive nature necessitate cautious formulation and use, making it generally questionable for broad application in precision skincare.


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