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SODIUM SESQUICARBONATE.

Questionable CAS 533-96-0 / BUFFERING, BULKING, CLEANSING

A mixed crystal of Sodium Carbonate and Sodium Bicarbonate, Sodium Sesquicarbonate functions primarily as a pH regulator and cleansing agent. It dissolves in water to create a mildly alkaline solution, which also helps to soften hard water.

pH Adjuster Buffering Cleansing Bulking Agent

Science

As a blended salt of sodium carbonate and bicarbonate, Sodium Sesquicarbonate moderates the pH of aqueous solutions, typically resulting in a mildly alkaline environment (e.g., pH 9.9 at 10% concentration or 10.1 for a 0.1M solution). Its bicarbonate component contributes to buffering capacity. Beyond pH adjustment, it acts as a cleansing agent and softens water by precipitating calcium and magnesium ions.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Commonly dusted

Sodium Sesquicarbonate can exist as a fine dust (known as Trona dust), which, due to its alkalinity (pH 10.5), has been noted to potentially irritate mucous membranes and skin upon exposure.


The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

Aqueous solutions are mildly alkaline (pH ~9.9-10.1), while its crystalline form is stable in air. It is cold water soluble, distinguishing it from Sodium Carbonate, and is particularly useful in formulations requiring additional buffering.

Conflicts

  • acids

Safety

CIR Status
Safe as used
Max tested
30.8%
Sensitization risk Moderate

The Cosmetic Ingredient Review (CIR) Expert Panel deemed Sodium Sesquicarbonate 'safe as presently used' in cosmetics, a conclusion reaffirmed in 2023. While historically used up to 50%, the maximum reported concentration in 'Other Skin Care Preparations' is 30.8%. It holds a Generally Recognized As Safe (GRAS) designation by the FDA for specific food uses. However, there are noted concerns regarding potential irritation, especially with prolonged exposure, on damaged skin, or when moisture is present.


Your Skin

No Normal
No Dry
No Oily
Yes Sensitive
Irritancy Medium
Comedogenicity Unknown

Our Assessment

Questionable

While effective as a pH adjuster and cleansing agent and deemed safe for cosmetic use up to 30.8%, its mild alkalinity and potential for irritation at higher concentrations or with prolonged exposure suggest careful consideration for precision skincare formulations, especially for sensitive skin.


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