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SODIUM PICRAMATE.

Avoid CAS 831-52-7 / HAIR DYEING

Sodium Picramate is a direct hair coloring agent primarily utilized for imparting temporary color by externally coating the hair shaft. It functions independently of oxidative coloring processes and is not recognized for direct active benefits within skincare formulations.

Colorant

Science

On hair, Sodium Picramate acts as a non-reactive direct colorant, depositing pigment onto the outer layer of the hair. It does not engage in the chemical oxidation mechanism typical of permanent dyes. In terms of skin interaction, it does not possess a specific beneficial mechanism; its presence on skin is generally incidental to its use as a hair dye.


Research

Insufficient-data confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

Dry Sodium Picramate is highly explosive and poses a significant fire hazard. It mandates storage with a minimum of 20% water content to mitigate explosion risks, indicating critical handling precautions for the raw material rather than a common dusting concern in final product formulations.


The Formula

Solubility
Water
Optimal pH 6.5 – 10
0 7 14

Stability

Sodium Picramate solutions in water exhibit stability for at least 48 hours. It remains stable within hair dye formulations formulated at a pH range of 6.5 to 10. While stability in oxidative formulations is suggested, supporting data has not been provided. Maintaining the material in a wet state is crucial for safety to prevent explosion hazards.


Safety

CIR Status
Safe as used
Max tested
0.1%
Sensitization risk Moderate

The Cosmetic Ingredient Review (CIR) Expert Panel determined Sodium Picramate safe for use as a hair dye at specified concentrations, citing minimal skin absorption. The Scientific Committee on Consumer Safety (SCCS) considers it safe for non-oxidative hair dyes with an on-head concentration of up to 0.6%. However, it has been identified as a moderate skin sensitizer with an Estimated Concentration (EC3) of 6.7% in a Local Lymph Node Assay. Human and guinea pig studies also reported it as a mild sensitizer at concentrations around 0.2% (picramic acid equivalent), leading to a recommended safe use limit in general cosmetic products of 0.1%. Dry Sodium Picramate is highly explosive, requiring a minimum of 20% water for safe handling. GHS hazard statements include 'Toxic if swallowed', 'Harmful in contact with skin', 'May cause an allergic skin reaction', and 'Harmful if inhaled'.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Avoid

Sodium Picramate is primarily a hair colorant with documented risks of skin sensitization and irritation, coupled with significant explosive hazards in its dry form, rendering it unsuitable for precision skincare formulations.


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