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SODIUM METAPHOSPHATE.

Valuable CAS 10361-03-2 / 50813-16-6 / BUFFERING, CHELATING, ORAL CARE

Sodium Metaphosphate is a polyphosphate compound primarily utilized in precision skincare formulations to maintain product integrity and enhance performance. It acts as a chelating agent to neutralize disruptive metallic ions, alongside serving as an emulsifier and stabilizer for optimal texture, and a pH regulator to support skin balance.

Chelating Agent Emulsifier Stabilizer pH Regulator

Science

This ingredient functions as a multi-faceted agent within cosmetic systems. As a chelating agent, it binds to metal ions, preventing them from destabilizing formulations and thus extending product shelf-life and efficacy. It further contributes as an emulsifier and stabilizer, promoting homogeneous textures and preventing ingredient separation. Additionally, it helps regulate the product's pH, which can support the skin's natural barrier function and improve the absorption and activity of other beneficial ingredients.


Research

Low confidence
Effective range 0.01–9.6%
Optimal

0.1%

Key findings

  1. 01 At a 1% concentration, Sodium Metaphosphate was found to be mildly irritating to the skin of human subjects in some safety assessments.
  2. 02 At a 1% concentration, Sodium Metaphosphate (and related polyphosphates) produced no irritation in contact allergy patients, indicating general tolerability in a sensitive population.

Transparency

Commonly dusted

Formulation considerations highlight 'dust generation' as a potential issue, indicating that this ingredient can create dust, which should be managed during handling.


The Formula

Solubility
Water
Optimal pH 5.8 – 7.3
0 7 14

Stability

Sodium Metaphosphate is stable in dry conditions. Its aqueous solution typically exhibits a pH between 5.8 and 7.3, but can be acidic and hydrolyze into phosphite over time. It is important to distinguish that while the general term 'Sodium Metaphosphate' may include practically insoluble long-chain forms, its common cosmetic derivatives like Sodium Hexametaphosphate and Sodium Trimetaphosphate are soluble in water.

Conflicts

  • incompatible materials
  • excess heat
  • strong acids
  • strong bases
  • pH mismatch with ingredients requiring different pH ranges for stability or efficacy

Safety

CIR Status
Safe with restrictions
Max tested
9.6%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) panel has determined Sodium Metaphosphate (and related polyphosphates) to be safe for cosmetic use when formulated to be non-irritating. Concentrations typically range from 0.01% to 9.6%, with higher levels in rinse-off products. In leave-on topical products, its use as a chelator is generally below 0.1%. Safety relies on appropriate formulation to avoid skin irritation, such as utilizing low concentrations in leave-on products or ensuring proper dilution.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Sodium Metaphosphate is a valuable formulation aid, crucial for maintaining product stability, texture, and pH balance, thereby indirectly supporting skin health with a generally low irritancy profile when properly formulated.


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