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SODIUM METABISULFITE.

Valuable CAS 7681-57-4 / 7757-74-6 / ANTIOXIDANT, PRESERVATIVE, REDUCING

Sodium Metabisulfite is a versatile inorganic salt primarily utilized in skincare formulations for its potent antioxidant and preservative properties. It effectively safeguards product integrity by inhibiting oxidation and microbial growth, thereby extending shelf life and maintaining ingredient efficacy.

Antioxidant Preservative Reducing Agent Anti-discoloration Agent pH Adjuster

Science

This compound acts as a powerful antioxidant by readily inhibiting oxidation processes, protecting sensitive ingredients from degradation induced by air, light, and free radicals. Its preservative function stems from its ability to suppress the proliferation of bacteria, fungi, and molds, enhancing product longevity. Additionally, it serves as a reducing agent, capable of modifying protein structures, and functions as an anti-discoloration agent to prevent oxidative color changes. It also contributes to formulation stability by acting as a pH adjuster. While some data suggests benefits for hyperpigmentation and acne-causing bacteria, its allergic contact dermatitis mechanism involves sulfite di-anions reacting with skin proteins.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

Sodium Metabisulfite is a functional ingredient typically included for its antioxidant and preservative capabilities, rather than as a primary active ingredient. As such, it is not commonly 'dusted' or over-marketed for exaggerated benefits.


The Formula

Solubility
Water
Optimal pH 3.5 – 5.5
0 7 14

Stability

This ingredient exhibits stability but is prone to slow oxidation into sulfate when exposed to air and moisture. Contact with water or moisture may result in the release of sulfur dioxide gas. It can react violently with concentrated sodium nitrite solutions.

Conflicts

  • Strong oxidizing agents (e.g., perchlorates, peroxides, permanganates, chlorates, nitrates, chlorine, bromine, fluorine)
  • Strong acids (e.g., hydrochloric acid, sulfuric acid, nitric acid)
  • Strong bases (e.g., sodium hydroxide, potassium hydroxide)
  • Air and moisture
  • Concentrated solutions of sodium nitrite
  • Aluminum powder

Safety

CIR Status
Safe as used
Max tested
5%
Sensitization risk Moderate

The CIR Expert Panel confirmed its safety in cosmetic formulations, specifically examining skincare products at concentrations under 1%. While SpecialChem indicates general safety up to 5% in cosmetics, reported use in rinse-off products has been up to 0.6%. The FDA recognizes it as Generally Recognized As Safe (GRAS) for food preservation, with certain limitations. Within the European Union, it is authorized as a preservative at a maximum concentration of 0.2%, calculated as free sulfur dioxide. Its chemistry suggests a potential for allergic contact dermatitis in susceptible individuals.


Your Skin

No Normal
No Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Valuable

Sodium Metabisulfite is a valuable functional ingredient for formulations requiring robust antioxidant protection and extended shelf life, though its use requires careful consideration for sensitive skin and adherence to regulatory concentration limits.


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