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SODIUM CITRATE.

Valuable CAS 68-04-2 / 6132-04-3 / BUFFERING, CHELATING, FRAGRANCE

Sodium Citrate is a salt derived from citric acid, a ubiquitous ingredient in precision skincare formulations. Its primary functions involve robust pH regulation and active chelation, crucial for maintaining product integrity and optimizing skin compatibility.

pH Adjuster Buffering Agent Chelating Agent Masking Agent Mild Preservative Preservative Booster Antioxidant Humectant Penetration Enhancer

Science

Sodium Citrate primarily functions as a precise pH adjuster and buffering agent, enabling cosmetic products to sustain an optimal pH level. This typically aligns with the skin's natural acid mantle (pH 4.5-5.5) but can effectively buffer solutions across a broader range of 3.0 to 6.2, preventing potential irritation and enhancing product compatibility. Concurrently, it acts as a potent chelating agent by binding to metal ions, such as calcium and magnesium, which might otherwise catalyze product degradation, discoloration, and diminish the efficacy of sensitive active ingredients and antioxidants. The ingredient also contributes mild preservative properties, inhibiting microbial proliferation and extending shelf life, often acting as a preservative booster. Additional benefits include potential antioxidant effects, contributing to protection against premature aging, and assisting other antioxidants in formulations. It may also function as a humectant to support skin hydration, a masking agent to neutralize undesirable odors, and potentially enhance the penetration of other beneficial compounds into the skin.


Research

Medium confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

Sodium Citrate serves fundamental roles in formulation stability and pH regulation, making its inclusion at effective concentrations essential rather than for marketing purposes.


The Formula

Solubility
Water
Optimal pH 3 – 6.2
0 7 14

Stability

Crucial for stabilizing product pH within the range of 3.0 to 6.2, ideally around the skin's natural pH of 4.5-5.5. Its chelating action prevents ingredient degradation, discoloration, and loss of efficacy by sequestering problematic metal ions. It notably improves the stability of sensitive actives like Vitamin C and helps prevent phase separation, particularly beneficial when formulating with certain natural emulsifiers. It is readily incorporated into the water phase, either from the start or during the cool-down phase.

Synergies

  • Enhances stability of Vitamin C
  • Supports other antioxidants
  • Works effectively with natural emulsifiers to maintain lotion stability
  • Boosts preservative efficacy

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded that Sodium Citrate, alongside citric acid and its esters, is safe for use in cosmetics and personal care products at current concentrations, showing no evidence of eye irritation, skin irritation, or allergic reactions. It is recognized as Generally Recognized as Safe (GRAS) by the FDA for direct food substances and receives a minimal hazard score of 1 from the Environmental Working Group (EWG). While broadly compatible with most skin types, including sensitive, caution and patch testing are advised for individuals with extremely sensitive or inflamed skin, or those with known hypersensitivity to citrus fruits, due to a rare potential for irritation or allergic response.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Sodium Citrate is a valuable excipient that critically ensures product stability, maintains optimal pH for skin health, and protects sensitive actives, thereby enhancing the overall efficacy and safety of skincare formulations.


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