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SODIUM BENZOATE.

Essential CAS 532-32-1 / ANTICORROSIVE, FRAGRANCE, PRESERVATIVE

Sodium benzoate is a widely utilized cosmetic preservative derived from benzoic acid. Its primary function is to safeguard formulations from microbial spoilage, extending product shelf life and ensuring consumer safety.

Preservative Deodorant

Science

This ingredient functions as an antimicrobial by inhibiting the proliferation of bacteria, molds, and other microorganisms in water-based products. It is the inactive salt of benzoic acid, which converts to its active form, benzoic acid, in acidic environments (pH below 4.0). In this active state, it predominantly acts as an anti-fungal agent with some antibacterial properties.


Research

High confidence
Effective range 0.1–0.5%
Optimal

0.5%

Key findings

  1. 01 Clinical assessments indicate that sodium benzoate is generally non-irritating to most skin types, including sensitive skin, when incorporated as a preservative at concentrations between 0.5% and 1.0%.

Transparency

Not commonly dusted

Sodium benzoate is a functional preservative, used at concentrations necessary to ensure microbial stability and product safety, adhering to regulatory limits. Its inclusion is for essential product integrity rather than being used at cosmetically insignificant or excessively high, non-functional levels.


The Formula

Solubility
Water
Optimal pH 2.5 – 4
0 7 14

Stability

Optimal antimicrobial efficacy is achieved in acidic conditions, specifically within a pH range of 2.5 to 4.0, where it converts into its active benzoic acid form. It also contributes to the pH stabilization of cosmetic formulations.

Conflicts

  • Vitamin C (ascorbic acid), particularly in the presence of heat and light, due to the potential for benzene formation.
  • Strong acids, which can lead to its premature decomposition into benzoic acid.

Safety

CIR Status
Safe with restrictions
Max tested
2.5%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) has determined Sodium Benzoate to be safe for use in cosmetics, subject to specific concentration and use limitations. European Union legislation permits its use up to 0.5% in leave-on products, 2.5% in rinse-off products, and 1.7% in oral care products. While generally recognized as safe (GRAS) for food by the FDA, a theoretical concern exists regarding benzene formation when combined with Vitamin C under specific conditions; however, the FDA indicates low levels in beverages do not pose a health risk.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Essential

Sodium Benzoate is an essential, highly effective, and generally well-tolerated preservative critical for maintaining the microbial stability and safety of water-based skincare formulations.


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