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QUATERNIUM-18.

Valuable CAS 61789-80-8 / ANTISTATIC, HAIR CONDITIONING, SURFACTANT - CLEANSING

Quaternium-18 is a versatile quaternary ammonium compound predominantly used for its conditioning, emulsifying, and mild surfactant properties. Its positively charged structure allows it to effectively interact with skin and hair, while its derivatives enhance product stability by suspending solids and regulating viscosity.

Antistatic Hair Conditioning Surfactant/Cleansing Emulsifier Suspending Agent Viscosity Controlling Agent

Science

As a positively charged quaternary ammonium compound, Quaternium-18 electrostatically binds to the negatively charged surfaces of skin and hair, delivering conditioning benefits. It functions as a mild surfactant for cleansing and acts as an emulsifier to stabilize immiscible oil and water phases. Its derivatives, specifically Quaternium-18 Bentonite and Quaternium-18 Hectorite, further contribute to formulation integrity by dispersing insoluble solids and controlling product viscosity.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH 4 – 6
0 7 14

Stability

Quaternium-18 clays, such as Quaternium-18 Hectorite and Bentonite, exhibit exceptional heat stability up to 500°C and maintain integrity against acid or base attacks within a broad pH range of 3-11.

Conflicts

  • Banned in certified organic cosmetics due to environmental toxicity and poor biodegradability.

Safety

CIR Status
Safe as used
Max tested
0.95%
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel consistently affirmed Quaternium-18 and its derivatives as safe for cosmetic use, with reaffirmations in 2001 and 2019/2020. Studies indicate poor skin absorption and minimal systemic effects from acute oral and percutaneous exposure. In humans, it demonstrated practically nonirritating and nonsensitizing properties. The FDA recognizes bentonite, a component of Quaternium-18 Bentonite, as Generally Recognized as Safe (GRAS) for direct food use. European applications are subject to compliance with EU regulations concerning animal by-products.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Quaternium-18 is a valuable multi-functional ingredient for conditioning, emulsification, and stability in skin and hair care, boasting a strong safety profile at concentrations up to 0.95%, though its environmental impact precludes its use in certified organic formulations.


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