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PROPYL GALLATE.

Valuable CAS 121-79-9 / ANTIOXIDANT, PERFUMING

Propyl Gallate is a precision antioxidant and free-radical scavenger primarily used to enhance the stability and shelf-life of skincare formulations by preventing degradation and rancidity of other ingredients.

antioxidant preservative free-radical scavenger

Science

As a potent antioxidant, Propyl Gallate neutralizes free radicals and inhibits oxidative reactions that can compromise product integrity, leading to issues like rancidity, discoloration, and deterioration of sensitive active ingredients. Beyond its primary role in product stabilization, research suggests potential secondary benefits including antimicrobial activity, enzyme inhibition, protection against UV radiation, and anti-inflammatory effects by modulating nitric oxide production.


Research

Insufficient-data confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Clinical repeat-insult patch tests demonstrated no irritation or sensitization from cosmetic formulations containing Propyl Gallate at concentrations as low as 0.003%.
  2. 02 Propyl Gallate was deemed non-sensitizing in topical applications at 0.1%, with CIR Expert Panel clinical experience confirming no sensitization reactions at this concentration.
  3. 03 Clinical cumulative irritancy tests indicated Propyl Gallate is non-irritating to the skin at concentrations up to 10%.

Transparency

Not commonly dusted
Red flag below
1%

Propyl Gallate functions effectively as a product stabilizer at low concentrations (e.g., FDA GRAS for food at 0.02%), making 'dusting' in the sense of ineffective inclusion for marketing unlikely. However, it is a confirmed dermal sensitizer at 1% or greater, and CIR recommends a maximum cosmetic concentration of 0.1% to mitigate sensitization risk; exceeding this represents a significant safety red flag.


The Formula

Solubility
Oil
Optimal pH 2 – 7
0 7 14

Stability

This ingredient maintains stability in neutral to slightly acidic environments, with its antioxidant efficacy peaking around pH 2. It is prone to instability when exposed to heat, mild alkaline conditions (which can cause ester bond hydrolysis), light, strong oxidizing agents, and metal ions. While sparingly soluble in water (1 mg/mL at 20°C), it exhibits excellent solubility in organic solvents and oils.

Conflicts

  • strong oxidizers
  • strong acids
  • strong bases
  • strong reducing agents
  • heat
  • alkaline environments
  • light
  • oxidizing agents
  • metal ions

Safety

CIR Status
Safe with restrictions
Max tested
0.1%
Sensitization risk Moderate

The Cosmetic Ingredient Review (CIR) Expert Panel deems Propyl Gallate safe for cosmetic use at concentrations not exceeding 0.1%. While it demonstrates dermal sensitizing properties at 1% and higher, and potentially below 1%, clinical use at or below 0.1% has shown no sensitization reactions. The FDA recognizes it as Generally Recognized As Safe (GRAS) for food at up to 0.02% of fat/oil content.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Propyl Gallate is a valuable ingredient primarily for stabilizing cosmetic formulations at concentrations up to 0.1%, effectively protecting product integrity and other active ingredients, though direct skin efficacy studies are limited and strict adherence to concentration limits is crucial to mitigate sensitization risks.


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