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POTASSIUM PERSULFATE.

Avoid CAS 7727-21-1 / OXIDISING

Potassium Persulfate is a powerful oxidizing agent primarily utilized in hair care formulations, such as lighteners and colorants, to chemically decolorize hair. While effective for its intended cosmetic purpose in hair, its application in skin-focused products is not supported by safety data due to known risks of irritation and sensitization.

Oxidizing Agent

Science

As a potent oxidizing agent, Potassium Persulfate operates by dissociating into peroxydisulfate dianions (S2O8)2- in solution. These further generate sulfate radical anions (SO4•–), which actively target and oxidize chromophores present in the hair shaft, leading to a lightening or decolorizing effect. Its mechanism is primarily observed in hair, not directly for skin benefits.


Research

Low confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Clinical observations indicate Potassium Persulfate is employed effectively in hair lighteners at concentrations reaching 60%.
  2. 02 Skin patch tests have revealed that concentrations exceeding 17.5% can trigger urticarial reactions, highlighting its potential for adverse cutaneous effects rather than benefits.

Transparency

Commonly dusted

As a white, crystalline solid, Potassium Persulfate presents a risk of airborne dust, which is a concern due to its potential to cause sensitization upon inhalation.


The Formula

Solubility
Water
Optimal pH 2.5 – 7
0 7 14

Stability

This odorless, white crystalline solid demonstrates stability at ambient room temperatures and possesses a robust shelf-life due to its minimal hygroscopy. Thermal decomposition begins around 65°C, accelerating significantly with increased temperature; for example, its half-life at 80°C is 1.5 hours compared to 1600 hours at 35°C. Aqueous solutions are acidic, typically ranging from pH 2.5 to 7. Storage requires a cool, dry, well-ventilated environment away from heat, direct sunlight, and humidity, in a tightly sealed container.

Conflicts

  • Organic compounds
  • Flammable materials
  • Combustible materials
  • Strong reducing agents
  • Dirt
  • Rust
  • Traces of metal
  • Reductants

Safety

CIR Status
Safe with restrictions
Max tested
60%
Sensitization risk High

The CIR Expert Panel deems Ammonium, Potassium, and Sodium Persulfates safe for brief, discontinuous use in hair colorants and lighteners, provided thorough rinsing follows application. Crucially, data is insufficient to establish safety for leave-on products or dentifrices. Concentrations above 17.5% are associated with urticarial reactions. Furthermore, it carries a high risk for sensitization via inhalation and skin contact, and is inherently irritating to the eyes, respiratory system, and skin.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Due to its primary application in hair decolorization, significant risks of skin irritation and sensitization, and insufficient safety data for leave-on topical use, Potassium Persulfate is unsuitable for precision skincare formulations.


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