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POLYSTEARYL METHACRYLATE.

Valuable CAS - / FILM FORMING

Polystearyl Methacrylate is a versatile polymer primarily utilized in skincare to create a remarkably smooth, velvety texture and to form a subtle, protective film on the skin. Its microscopic spherical particles also possess light-scattering properties, contributing a desirable soft-focus effect that optically blurs imperfections.

film forming texture enhancer soft focus agent

Science

As a large polymer, Polystearyl Methacrylate primarily functions by forming a coherent, flexible film on the skin's surface, enhancing product longevity and wear. Its unique spherical microstructure allows for effective light scattering, which diffuses light and creates an optical blurring effect to minimize the appearance of fine lines and uneven skin tone. Additionally, it acts as a texture enhancer, imparting an exceptional smoothness and a luxurious velvety feel to formulations upon application.


Research

Low confidence
Effective range 0.01–45%
Optimal

N/A

Key findings

  1. 01 Polymethyl Methacrylate (PMMA), a structurally related polymer frequently used in cosmetics as microspheres for film-forming and texture enhancement, has been observed in formulations at concentrations ranging from 0.01% to 45%.
  2. 02 In specific dental resin compositions, stearyl methacrylate levels between 12.5% and 25% (wt%) were found crucial for optimizing mechanical properties and reducing water absorption. It is important to note this research pertains to dental materials and not direct topical skincare applications.

Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH N/A
0 7 14

Stability

Polystearyl Methacrylate (PSMA) is inherently insoluble in water. However, its water solubility can be influenced in copolymer forms if the stearyl methacrylate content is below 17 mol%, and can potentially be enhanced by the strategic incorporation of an organic co-solvent. It demonstrates good solubility in apolar solvents like hexane and aromatic solvents such as toluene.

Conflicts

  • Acidic resin monomers can potentially deactivate tertiary amines in chemically-cured resin systems, which might impact polymerization processes.
  • Formulations must ensure residual levels of uncured methacrylate monomers are minimized to prevent potential irritation or toxicity to the skin.

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded that Polystearyl Methacrylate is safe for use in cosmetics under current practices and concentrations, provided formulations are non-irritating. As a fully polymerized, large molecule, it is not expected to significantly penetrate the stratum corneum, thereby limiting systemic exposure. While uncured methacrylate monomers can be irritating, their concentrations in cosmetic products are typically kept low and are not considered a safety concern.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Polystearyl Methacrylate is a valuable polymeric ingredient for enhancing product aesthetics and sensorial experience, offering reliable film-forming, texture-improving, and soft-focus benefits across a range of cosmetic formulations.


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