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POLYHYDROXYETHYLMETHACRYLATE.

Valuable CAS 25249-16-5 / BINDING

Polyhydroxyethylmethacrylate is a hydrophilic polymer that forms a robust hydrogel, capable of absorbing 10% to 600% of its dry weight in water. This multifunctional ingredient acts as a film former, significantly enhancing product texture by imparting a smooth, velvety feel, and can provide a subtle soft-focus effect.

Film Former Texture Enhancer Soft Focus Agent Viscosity Increasing Agent

Science

As a poly(2-hydroxyethyl methacrylate), or pHEMA, this polymer is inherently hydrophilic, enabling it to readily form a hydrogel upon contact with water. Its capacity to absorb between 10% and 600% of its dry weight in water allows it to swell and create a stable, gel-like structure. In cosmetic applications, it establishes a uniform film on the skin's surface, contributing to an enhanced sensorial experience with a smooth and velvety texture. When present as polymer microspheres, it can scatter incident light, thereby creating a diffused, soft-focus, or blurring visual effect. The presence of multiple hydroxyl groups within its molecular structure facilitates broad interaction with other ingredients.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 1 – 13
0 7 14

Stability

PHEMA hydrogels exhibit considerable mechanical strength and maintain stability across a wide pH range, specifically from 1 to 13. This robustness is attributed to their inherently stable cross-linking structures. Furthermore, the polymer demonstrates solubility in ethanol, with documented concentrations up to 120 mg/mL.


Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded that Polyhydroxyethylmethacrylate is safe for use in cosmetics when formulated to be non-irritating and applied within current practices and concentrations. The FDA highlights its biocompatibility by permanently listing specific Poly(Hydroxyethyl Methacrylate)-dye copolymers as exempt from certification for coloring medical devices such as contact lenses, with usage restricted to the minimum amount required for the intended coloring effect.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Polyhydroxyethylmethacrylate is a valuable polymer for skincare formulations, offering advanced textural enhancement and film-forming properties with a robust safety profile and broad skin compatibility.


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