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POLOXAMER 333.

Valuable CAS 9003-11-6 / SURFACTANT - CLEANSING, SURFACTANT - EMULSIFYING

Poloxamer 333 is a nonionic triblock copolymer primarily utilized as a surfactant and emulsifier in skincare formulations. Its unique structure enables it to reduce surface tension, effectively blending oil and water-based ingredients for stable product consistency and enhanced cleansing properties.

surfactant/cleansing emulsifying solubilizing

Science

As a nonionic triblock copolymer, Poloxamer 333 comprises a hydrophobic core of polyoxypropylene flanked by two hydrophilic chains of polyoxyethylene. This structure allows it to function as a highly effective surfactant, reducing the surface tension between different phases. This action facilitates the formation of stable emulsions, solubilizes otherwise insoluble ingredients, and acts as a cleansing agent by helping water mix with oils and impurities, allowing them to be easily rinsed away from the skin.


Research

Low confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Demonstrated antibacterial activity, achieving 90% inhibition of Mycobacterium avium complex.
  2. 02 Surface concentrations within this range in tissue engineering applications promoted rapid cell growth and inhibited platelet adhesion/activation.

Transparency

Not commonly dusted

No data suggesting Poloxamer 333 is commonly 'dusted' or used below effective percentages for claimed benefits in cosmetic applications.


The Formula

Solubility
Both
Optimal pH N/A
0 7 14

Stability

Poloxamers are known to form micelles, hydrogels, and lyotropic liquid crystals, with their phase behavior being sensitive to temperature. Rigorous purification steps are essential during manufacturing to maintain purity and control levels of impurities such as 1,4-dioxane, ethylene oxide, and propylene oxide.


Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel concluded that Poloxamer 333, like other Poloxamers, is safe for use in cosmetics, citing consistently negative results in dermal irritation and sensitization tests. Due to its molecular weight and solubility, skin penetration is expected to be minimal. The CIR Panel emphasizes the necessity for the cosmetic industry to uphold stringent purification processes to keep trace impurities like 1,4-dioxane, ethylene oxide, and propylene oxide below established regulatory limits. It is also recognized by the FDA as an indirect food additive, approved for incidental food contact in sanitizing solutions.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Poloxamer 333 is a valuable nonionic copolymer essential for formulation stability, effective cleansing, and solubilization in a wide range of cosmetic products, recognized for its low sensitization risk.


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