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PIGMENT RED 4.

Questionable CAS 2814-77-9 / HAIR DYEING

Pigment Red 4, also known as CI 12085 or D&C Red No. 36, is a synthetic monoazo organic pigment primarily utilized in cosmetic formulations to impart a vivid yellowish-red to brilliant red coloration, thereby enhancing product aesthetics.

cosmetic colorant

Science

This ingredient functions as a cosmetic colorant by physically reflecting specific wavelengths of light, delivering a precise red hue to topical formulations. It does not exhibit any active biological mechanism on the skin itself.


Research

Low confidence
Effective range N/A
Optimal

3%


Transparency

Not commonly dusted

Pigment Red 4 is typically incorporated into formulations at a maximum concentration of 3%, a quantity not associated with the micro-dosing concerns of highly potent ingredients requiring stringent dusting controls.


The Formula

Solubility
Oil
Optimal pH 5.5 – 8
0 7 14

Stability

Pigment Red 4 exhibits robust resistance to acids, alkalis, alcohol, and water, maintaining optimal stability within a pH range of 5.5 to 8.0. It possesses a medium lightfastness rating of Grade 6, indicating potential darkening upon prolonged solar exposure. While some sources note poor general heat resistance, it tolerates temperatures up to 140°C-180°C for short durations.


Safety

CIR Status
Deferred evaluation
Max tested
3%
Sensitization risk High

The Cosmetic Ingredient Review (CIR) has deferred evaluation, citing assessment by the U.S. FDA, which approves Pigment Red 4 (D&C Red No. 36) for use in externally applied cosmetics, including lip products, at a maximum concentration of 3%. Importantly, it is strictly prohibited for use in the eye area. The European Union's SCCS approves its use without specific restrictions. However, Canada and China also impose a 3.0% maximum concentration, with China additionally forbidding its use in hair dye products. As a member of the azo dye family, it is associated with broader concerns regarding potential mutagenicity, genotoxicity, and carcinogenicity. Certain individuals, particularly those with sensitive skin, may experience mild irritation or allergic reactions. The Environmental Working Group (EWG) assigns a high rating for use restrictions.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Questionable

Pigment Red 4 serves as an FDA-approved colorant providing vibrant red hues for external cosmetic applications up to 3%; however, its association with the azo dye family, potential for sensitive skin irritation, and high regulatory restrictions warrant a cautious formulation approach.


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