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PHTHALIC ANHYDRIDE.

Avoid CAS 85-44-9 / NOT REPORTED

Phthalic Anhydride is an industrial chemical historically utilized in some cosmetic formulations for its plasticizing and fixative properties. However, it is widely recognized as a hazardous substance due to its potent irritant and sensitizing effects on human skin.

Industrial chemical intermediate (for plasticizers, resins, dyes) Plasticizer (hair care, historical) Adhesion enhancer (nail polishes, historical) Fixative (fragrances, historical)

Science

Upon contact with water, Phthalic Anhydride undergoes hydrolysis, forming phthalic acid. This resulting acid is a significant skin irritant, capable of inducing contact dermatitis characterized by redness, a burning sensation, and potentially leading to dryness, chapping, or urticaria with continued exposure. The ingredient also carries a demonstrable risk of inducing skin sensitization.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

Phthalic Anhydride is consistently classified as a hazardous substance by regulatory bodies and safety organizations. There is no scientific basis or industry practice to suggest this ingredient is commonly misrepresented as beneficial in skincare; instead, its adverse effects are widely acknowledged.


The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

This ingredient is hydrolytically unstable, reacting slowly with water to form phthalic acid. Its half-life in water is approximately 30.5 seconds at pH 7.24 and 61 seconds at pH 6.8, demonstrating rapid degradation in aqueous environments, particularly at common formulation pH levels (4, 7, and 9).

Conflicts

  • Water
  • Alkalis
  • Alcohols
  • Oxygen
  • Oxidizing agents
  • Strong acids
  • Strong bases
  • Reducing agents
  • Copper oxide (on heating)
  • Sodium nitrite (on heating)

Safety

CIR Status
Not reviewed
Sensitization risk High

The European Union (EU GHS) classifies Phthalic Anhydride as harmful if swallowed, causing serious eye damage, skin irritation, and potentially allergic skin reactions. It can also lead to allergy or asthma symptoms if inhaled. While the EPA has not classified it for carcinogenicity, and the FDA monitors phthalates (derivatives) in cosmetics, stating no evidence of risk from phthalates currently used, Phthalic Anhydride itself is explicitly recognized as a hazardous substance. EWG rates it as 'Unacceptable' for product use, and occupational exposure limits are extremely low (e.g., TLV of 0.002 mg/m³).


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Phthalic Anhydride is a highly irritating and sensitizing hazardous substance with no demonstrable benefits for skin, rendering it entirely unsuitable for precision skincare formulations.


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