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PEG-4 DISTEARATE.

Valuable CAS 9005-08-7 / SURFACTANT - EMULSIFYING

PEG-4 Distearate is a versatile polyethylene glycol ester that serves as an effective emulsifier, solubilizer, and viscosity controller. It is instrumental in creating stable formulations by blending disparate ingredients and enhancing product texture through controlled thickening.

emollient emulsifying viscosity controlling

Science

This ingredient functions by lowering the surface tension between immiscible substances, allowing oil and water phases to combine stably, which is crucial for emulsification and effective cleansing. It also acts as a solubilizer for ingredients not typically soluble in a given solvent, and as an associative thickener, significantly contributing to the desired viscosity of a formulation.


Research

High confidence
Effective range 0.5–5%
Optimal

N/A

Key findings

  1. 01 Demonstrated efficacy as a thickening agent in cosmetic formulations within a concentration range of 0.5% to 5%.

Transparency

Not commonly dusted

Given its fundamental roles in emulsification, solubilization, and viscosity control, PEG-4 Distearate is considered an essential functional ingredient rather than one commonly 'dusted' or superfluously included in formulations.


The Formula

Solubility
Water
Optimal pH 5 – 8
0 7 14

Stability

PEG-4 Distearate exhibits chemical stability under standard ambient conditions and generally maintains integrity in the presence of electrolytes and weak acids or bases. However, strong acids or bases can trigger gradual hydrolysis and saponification. Optimal formulation performance is observed within a pH range of 5 to 8. For incorporation, it is advisable to heat PEG-4 Distearate with other surfactants to 60°C until fully melted, then integrate into the water phase at 35°C before adding the oil phase.

Conflicts

  • Hot alkaline solutions (risk of hydrolysis)
  • Strong acids or bases (risk of saponification)
  • Salicylates (potential for discoloration or precipitation)
  • Phenolic substances (potential for discoloration or precipitation)
  • Iodine salts (potential for discoloration or precipitation)
  • Salts of bismuth, silver, and tannins (potential for discoloration or precipitation)
  • Certain preservatives (e.g., bacitracin, chloramphenicol, tetracycline) at concentrations >5% w/w, due to potential complex formation reducing antimicrobial activity.

Safety

CIR Status
Safe as used
Max tested
5%
Sensitization risk Low

The CIR Expert Panel has determined PEG-4 Distearate to be safe for use in cosmetic formulations. It demonstrates low toxicity and a minimal likelihood of causing skin irritation or sensitization. While ethoxylation processes may generate trace amounts of 1,4-dioxane, reputable manufacturers ensure strict control through purification. This ingredient aligns with global cosmetic safety standards, including US FDA regulations.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

PEG-4 Distearate is a valuable ingredient, effectively providing essential emulsifying, solubilizing, and viscosity-controlling properties in a broad spectrum of cosmetic and personal care formulations with a low risk of irritation or sensitization.


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