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PEG-12.

Valuable CAS 25322-68-3 / HUMECTANT, SOLVENT

PEG-12 is a polyethylene glycol derivative prized for its dual functionality as a humectant and solvent in precision skincare. It actively draws and delivers moisture to the skin, while ensuring uniform distribution of other active ingredients for enhanced product texture and efficacy.

Humectant Solvent Emollient Emulsifying Surfactant/Cleansing

Science

As a humectant, PEG-12 attracts water to the skin's outer layers, forming hydrogen bonds with water molecules to provide sustained hydration and reduce water evaporation by forming a light barrier. Beyond hydration, it acts as a solvent, critical for the uniform mixing and even distribution of formulation components. When chemically modified into PEG-12 Dimethicone, it further enhances hydration by creating a breathable film that locks in moisture, optimizes product spreadability, and improves the absorption of beneficial ingredients, simultaneously acting as an emulsifier to impart a smooth, velvety skin feel.


Research

Medium confidence
Effective range 1–5%
Optimal

Optimal usage concentrations for PEG-12 Dimethicone range from 1% for lightweight serums up to 5% for richer creams to enhance emulsion stability, texture, and sensory properties.

Key findings

  1. 01 Demonstrated ability to enhance emulsion stability, texture, and sensory properties in formulations, specifically observed with PEG-12 Dimethicone.

Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH 5.5 – 7
0 7 14

Stability

PEG-12 exhibits optimal stability within a neutral to slightly acidic pH range of 5.5 to 7.0, ensuring compatibility with most personal care systems. PEG solutions may experience a reduction in pH over time due to aging, a process accelerated by warm temperatures, light, and oxygen. Storing at colder temperatures (-20°C or 4°C) and purging containers with argon can minimize these degradation effects. PEG-12 Dimethicone specifically demonstrates stability in water-based systems.

Conflicts

  • Stearyl alcohol (for PEG-12 Dimethicone)
  • Stearic acid (for PEG-12 Dimethicone)
  • IPM (Isopropyl Myristate) (for PEG-12 Dimethicone)
  • Beeswax (for PEG-12 Dimethicone)
  • Glycerol (for PEG-12 Dimethicone)
  • Lanolin (for PEG-12 Dimethicone)
  • Mineral Oil (for PEG-12 Dimethicone)
  • Paraffin wax (for PEG-12 Dimethicone)
  • Dimethicone, 350cSt (for PEG-12 Dimethicone)

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel concluded that polyethylene glycol ingredients, including PEG-12, are safe for use in cosmetics, citing low oral and dermal toxicity, minimal irritation to human skin, and no sensitizing effects on intact skin. A 2010 re-review removed previous caveats regarding use on damaged skin, clarifying that significant penetration only occurs with severely compromised skin (second and third-degree burns). The FDA also recognizes PEGs as Generally Recognized As Safe (GRAS). However, the ethoxylation manufacturing process can result in trace amounts of 1,4-dioxane, a potential impurity, which can be effectively controlled through purification steps. It is important to note that PEG-12 Dimethicone has been classified as a 'moderate hazard' by some databases due to these potential contamination concerns.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

PEG-12 is a valuable ingredient for enhancing hydration and product formulation, demonstrating broad skin compatibility and a low risk profile on intact skin, with careful consideration for potential trace impurities.


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