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MORPHOLINOPROPANE SULFONIC ACID.

Valuable CAS 1132-61-2 / BLEACHING, BUFFERING

Morpholinopropane Sulfonic Acid (MOPS) is a zwitterionic Good's buffer, adept at precisely stabilizing pH in aqueous solutions. Its chemical structure enables it to absorb or release protons, ensuring optimal acidity levels essential for product stability and compatibility with biological systems.

Buffering agent pH adjuster

Science

As a zwitterionic Good's buffer, MOPS primarily operates by maintaining a stable pH within aqueous formulations, a crucial factor for ensuring ingredient efficacy and product integrity. In biological contexts, concentrations above approximately 0.41852% have been observed to interact with lipid membranes, potentially influencing their permeability and barrier function.


Research

Medium confidence
Effective range 0.209–2.09%
Optimal

N/A

Key findings

  1. 01 Effective buffering capacity is directly correlated with concentration within this range.
  2. 02 Potential for altering lipid membranes, affecting cell permeability, and decreasing glucose uptake.

Transparency

Commonly dusted
Min. effective
0.41852%
Red flag below
0.41852%

At concentrations equal to or exceeding 0.41852% (20 mM), MOPS has been shown to disrupt lipid membranes in mammalian cell culture, compromising cell permeability and reducing glucose uptake by 15-20%. This critical threshold suggests potential for adverse cellular interactions if used at elevated percentages in dermal formulations.


The Formula

Solubility
Water
Optimal pH 6.5 – 7.9
0 7 14

Stability

MOPS is stable under normal conditions, offering optimal buffering efficacy within a pH range of 6.5 to 7.9. While solutions may discolour to yellow over time, this typically does not impair its buffering characteristics. It also exhibits robust metal-buffer stability, demonstrating no interaction with common metal ions like copper, nickel, manganese, zinc, and cobalt.

Synergies

  • Stable with common metal ions (e.g., copper, nickel, manganese, zinc, cobalt)

Conflicts

  • strong bases
  • strong oxidizing agents
  • hydrogen peroxide (slow oxidation to N-oxide form)

Safety

CIR Status
Not reviewed
Max tested
0.41852%
Sensitization risk Moderate

While generally described as non-toxic and having a low environmental impact in laboratory settings, GHS classifications indicate Morpholinopropane Sulfonic Acid can cause skin irritation (H315), serious eye irritation (H319), and respiratory irritation (H335). There are currently no published specific safety assessments for cosmetic use by the Cosmetic Ingredient Review (CIR) or Scientific Committee on Consumer Safety (SCCS). For precision, we advise against exceeding 0.41852% based on mammalian cell culture data.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Valuable

Morpholinopropane Sulfonic Acid is a valuable buffering agent, critical for maintaining optimal product pH, though its concentration requires careful consideration due to potential cellular interactions at higher levels.


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