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METHYLPARABEN.

Valuable CAS 99-76-3 / FRAGRANCE, PRESERVATIVE

Methylparaben is a highly effective, broad-spectrum antimicrobial preservative utilized in skincare to prevent the growth of bacteria, mold, and yeast. It ensures product stability and safety, particularly in water-based formulations, maintaining integrity for extended periods.

preservative

Science

This paraben derivative functions by disrupting cellular membrane transfer processes and inhibiting the synthesis of vital macromolecules like DNA, RNA, and enzymes within bacterial cells. Its antimicrobial efficacy is pH-dependent, with optimal activity observed when the molecule is in its undissociated acid form, meaning greater potency is typically achieved at lower pH levels.


Research

High confidence
Effective range 0.1–0.4%
Optimal

0.2%


Transparency

Not commonly dusted

As a crucial preservative, Methylparaben is incorporated into formulations at effective concentrations (typically 0.1-0.3%) to ensure product safety and microbiological stability. This necessary functional role means it is not 'dusted' at ineffectual levels, unlike some active ingredients for skin benefits.


The Formula

Solubility
Both
Optimal pH 3 – 6
0 7 14

Stability

Aqueous solutions of Methylparaben exhibit high stability, demonstrating less than 10% decomposition over approximately four years at room temperature within a pH range of 3 to 6. It can withstand sterilization via autoclaving at 120°C for 20 minutes without decomposition but undergoes rapid hydrolysis at pH levels of 8 or higher, leading to significant degradation within 60 days.

Synergies

  • Often used in combination with other paraben esters to provide broader antimicrobial coverage, with regulatory guidance stipulating a total paraben concentration not exceeding 0.8% (as acid) for mixtures.

Conflicts

  • Bentonite
  • Magnesium trisilicate
  • Talc
  • Tragacanth
  • Sodium alginate
  • Essential oils
  • Sorbitol
  • Atropine
  • Various sugars and related sugar alcohols
  • Iron (may cause discoloration)
  • Certain plastics (potential for absorption, excluding low-density and high-density polyethylene)

Safety

CIR Status
Safe as used
Max tested
0.4%
Pregnancy
Safe
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded Methylparaben is safe for use in cosmetics under current practices and concentrations, provided the sum of combined paraben concentration in any given formulation does not exceed 0.8%. The Scientific Committee on Consumer Safety (SCCS) deems its use safe up to 0.4% when employed alone, or up to 0.4% within a mixture of esters, where the total ester concentration does not surpass 0.8% (all expressed as acid). Despite concerns regarding potential endocrine disrupting properties, both SCCS and the FDA have concluded its safety at these established concentrations, with the FDA stating no current information demonstrates adverse human health effects from paraben use in cosmetics. Methylparaben is also Generally Recognized As Safe (GRAS) by the US FDA for food and cosmetic antibacterial preservation.


Your Skin

Yes Normal
No Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Methylparaben is a valuable and extensively reviewed preservative, essential for maintaining the microbiological integrity and safety of a wide array of cosmetic formulations at carefully controlled and regulated concentrations.


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