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METHYL THIOGLYCOLATE.

Avoid CAS 2365-48-2 / HAIR WAVING OR STRAIGHTENING

Methyl Thioglycolate is an ester derivative of Thioglycolic Acid, primarily utilized for its ability to alter hair structure. It functions as a potent reducing agent, facilitating changes in hair fibers for applications such as permanent waving or hair removal.

depilatory hair waving or straightening reducing

Science

This ingredient operates by chemically disrupting the disulfide bonds found within the keratin protein structure of hair. This molecular alteration allows for hair fibers to be easily reshaped during waving or straightening processes, or efficiently removed in depilatory formulations.


Research

High confidence
Effective range 5–15.2%
Optimal

8%


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 7 – 12.7
0 7 14

Stability

Methyl Thioglycolate has a pKa of 8.08. Its parent compound, Thioglycolic Acid, is prone to oxidation upon exposure to air and exhibits superior stability when stored in glass containers compared to polyolefin bottles.

Conflicts

  • strong bases
  • heat, sparks, open flames, and other ignition sources (flammable liquid and vapor)

Safety

CIR Status
Safe with restrictions
Max tested
15.2%
Sensitization risk High

The CIR Expert Panel determined Methyl Thioglycolate is safe for use in specified hair products up to 15.2% (as Thioglycolic Acid equivalent), but critically advises hairdressers to avoid skin contact and minimize consumer exposure. The parent compound, Thioglycolic Acid, is classified as a severe skin and eye irritant (Skin Corr. 1B; H314), capable of causing severe skin burns and eye damage. Use is strictly regulated by concentration and pH.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Medium
Comedogenicity Unknown

Our Assessment

Avoid

Due to its potent hair-modifying action and the significant risk of severe skin irritation and burns associated with its use, Methyl Thioglycolate is not suitable for general skincare formulations and should be avoided in products intended for direct skin application.


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