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METHYL NICOTINATE.

Valuable CAS 93-60-7 / SOOTHING, TONIC

Methyl Nicotinate is a pyridine derivative functioning as a topical rubefacient and vasodilator. It rapidly enhances cutaneous microcirculation, which manifests as temporary local erythema and a distinct warming or tingling sensation. This ingredient is leveraged to improve skin appearance and deliver targeted circulatory benefits.

Skin-Conditioning Agent Vasodilator Rubefacient Toning

Science

Upon topical application, Methyl Nicotinate functions as a rubefacient and vasodilator. Its primary mechanism involves stimulating the release of prostaglandin D2, which acts on capillary endothelial cells to induce localized cutaneous vasodilation. This process, also influenced by local sensory nerve activation, significantly increases microcirculation, resulting in temporary skin erythema and a distinct warming or tingling sensation.


Research

High confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Topical application of 20 mmol/L Methyl Nicotinate reliably induced a microvascular response in the skin, reaching a plateau between 5 and 20 minutes post-application.
  2. 02 Formulations containing 0.5% and 1.0% Methyl Nicotinate elicited a maximal skin response within 30 minutes, characterized by increased microcirculation, transepidermal water loss, and transient dermal edema.
  3. 03 Concentrations exceeding 10^-4 mol/L were shown to significantly enhance local blood flow.

Transparency

Not commonly dusted

The Formula

Solubility
Both
Optimal pH N/A
0 7 14

Stability

Methyl Nicotinate demonstrates excellent chemical and biological stability in aqueous solutions when stored at 4°C. Its gradual degradation to nicotinic acid (approximately 0.5% per annum) does not significantly compromise its vasodilatory efficacy over prolonged storage periods, up to 1057 days. It maintains stability under standard handling and storage conditions.


Safety

CIR Status
Deferred evaluation
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) has deferred evaluation, deferring to the FDA's assessment. The FDA has approved Methyl Nicotinate for use in Over-The-Counter (OTC) external analgesics (counter-irritants). It is known to induce local skin erythema and a warming/tingling sensation. It carries GHS hazard statements H315 (Causes skin irritation) and H319 (Causes serious eye irritation). However, EWG Skin Deep rates it as low risk for cancer, allergies & immunotoxicity, developmental and reproductive toxicity, and use restrictions.


Your Skin

No Normal
Yes Dry
No Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Valuable

Methyl Nicotinate is a valuable active for targeted applications requiring enhanced microcirculation and skin conditioning, but its irritancy necessitates careful formulation and consideration for sensitive skin types.


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