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MALIC ACID.

Valuable CAS 97-67-6 / BUFFERING

Malic acid is a gentle alpha hydroxy acid (AHA) recognized for its dual exfoliating and humectant properties. It effectively refines skin texture and enhances brightness by promoting cellular renewal, while simultaneously boosting skin hydration, making it broadly compatible with various skin types.

Exfoliant Humectant Buffering Agent pH Adjuster Antioxidant Collagen Booster

Science

As an alpha hydroxy acid, malic acid primarily functions by gently dissolving the 'glue' (intercellular bonds) between dead skin cells on the skin's uppermost layer. This action facilitates the shedding of old cells, thereby stimulating skin renewal and accelerating cellular turnover. Beyond its exfoliating role, malic acid acts as a humectant, attracting and retaining moisture in the skin to enhance hydration. It also contributes to restoring skin's optimal pH balance, supports collagen production, and offers beneficial antioxidant qualities.


Research

High confidence
Effective range 1–10%
Optimal

1%

Key findings

  1. 01 Concentrations between 1-2% demonstrate gentle exfoliation, leading to improved overall skin texture, smoother, and brighter skin. It can also enhance the efficacy of other AHA exfoliants.
  2. 02 Formulations containing up to 1% malic acid were not identified as significant skin irritants and did not induce allergic contact dermatitis.
  3. 03 While concentrations up to 10% are considered safe for home use when formulated to maintain a pH of 3.5 or higher and are associated with reduced sun sensitivity, a 5% concentration in an aqueous solution has shown skin irritation (mean irritation score 0.86).

Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 3 – 4
0 7 14

Stability

For optimal efficacy as a mild exfoliant, malic acid formulations should ideally maintain a pH between 3.0 and 4.0. The ingredient itself typically exhibits a pH between 3.0 and 3.5. It is stable but requires storage in a cold, dry place to prevent degradation.

Conflicts

  • Other strong exfoliants (e.g., in the same routine, can cause irritation)
  • Retinoids (e.g., in the same routine, can cause irritation)
  • Combining with other AHAs may cause redness, peeling, dryness, inflammation, or irritation

Safety

CIR Status
Safe as used
Max tested
10%
Sensitization risk Low

The CIR Expert Panel concluded that malic acid is safe for cosmetic use under current practices. Concentrations up to 1% in formulation were found not to be significant skin irritants and did not induce allergic contact dermatitis. However, concentrations like 5% in aqueous solution have demonstrated skin irritation. It is classified as an ocular irritant, and incidental eye exposure, particularly from products like hair sprays, should be minimized. FDA classifies malic acid as GRAS ('Generally Recognized as Safe').


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low to medium
Comedogenicity Unknown

Our Assessment

Valuable

Malic acid is a valuable, gentle AHA that improves skin texture and hydration across all skin types, with a favorable safety profile at appropriate concentrations and careful formulation.


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