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HYDROXYPROPYL GUAR HYDROXYPROPYLTRIMONIUM CHLORIDE.

Valuable CAS 71329-50-5 / ANTISTATIC, HAIR CONDITIONING

A cationic polymer derived from guar gum, Hydroxypropyl Guar Hydroxypropyltrimonium Chloride functions as an excellent skin and hair conditioning agent, humectant, and texture enhancer. It forms a smoothing film, contributing to enhanced product feel and formulation stability.

Antistatic Hair conditioning Skin conditioning Humectant Viscosity controlling Film forming

Science

This ingredient operates as a cationic polymer, utilizing its positively charged trimethylammonium groups to electrostatically bind with the inherently negatively charged surfaces of skin and hair. This interaction creates a thin, conditioning film that imparts a soft, smooth, and hydrated sensation. Beyond its primary conditioning role, it also acts as a humectant, attracting and retaining moisture. Furthermore, it significantly improves product viscosity and overall formulation stability, while mitigating the potentially stiffening effects of surfactants and contributing to the skin's pH buffering capacity.


Research

Medium confidence
Effective range 0.1–1%
Optimal

For optimal conditioning and viscosity, concentrations between 0.1% and 1.0% are typically employed. Hair care often utilizes lower concentrations, from 0.1% to 0.3%, for exceptional conditioning benefits.


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 6 – 7
0 7 14

Stability

This ingredient demonstrates water solubility and is stable across a broad pH range typical for cosmetic applications. While the powder itself maintains a pH of 6-7, some grades may exhibit a higher pH up to 10.5 in solution. For optimal performance and immediate viscosity development, adjusting the dispersion's pH to approximately 6 with citric acid after hydration is recommended. It is self-hydrating and compatible with most common anionic, cationic, and amphoteric surfactants, forming a conditioning coacervate with anionic surfactants upon dilution.

Synergies

  • Anionic surfactants (forms coacervate for enhanced conditioning deposition)
  • Cationic surfactants
  • Amphoteric surfactants

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has deemed Hydroxypropyl Guar Hydroxypropyltrimonium Chloride safe for use in cosmetics and personal care products under normal conditions. It is characterized as non-irritating, non-sensitizing, and biodegradable at typical use concentrations. However, concentrations exceeding 1.0% may pose a minimal risk of irritation, particularly for individuals with sensitive skin, necessitating patch testing for such applications. The FDA participates in the CIR expert panel, and related guar derivatives are listed as indirect food additives. No specific SCCS opinion is currently available.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

Hydroxypropyl Guar Hydroxypropyltrimonium Chloride is a valuable conditioning and texturizing agent, providing skin and hair with a smooth, hydrated feel and enhancing product formulation stability, particularly effective within its recommended use concentrations.


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