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HINOKITIOL.

Valuable CAS 499-44-5 / ANTISTATIC, HAIR CONDITIONING

Hinokitiol is a naturally derived tropolone compound celebrated for its potent multi-functional properties. It acts as a broad-spectrum antimicrobial, a powerful antioxidant, and an effective anti-inflammatory agent, making it a valuable ingredient for diverse skin concerns. Additionally, it contributes to skin brightening by inhibiting melanin production.

Antimicrobial Antibacterial Antioxidant Anti-inflammatory Preservative Antiacne Skin Brightening

Science

Hinokitiol exerts its antibacterial action by disrupting bacterial cell membrane metabolism, affecting respiration and permeability, akin to other phenolic compounds. Its significant metal-chelating capacity allows it to bind essential metal ions like iron, zinc, and copper, acting as an ionophore to accelerate their cellular uptake, which can induce reactive oxygen species and inhibit vital iron-dependent enzymes. This mechanism underpins its broad antimicrobial efficacy. Furthermore, Hinokitiol reduces inflammation in skin cells through unspecified pathways, combats oxidative stress as an antioxidant, and promotes a brighter complexion by inhibiting tyrosinase, the enzyme crucial for melanin synthesis.


Research

High confidence
Effective range 0.00003–0.0194%
Optimal

Efficacy observed across a range, typically 0.00003% to 0.01% for specific antimicrobial effects, and up to approximately 0.0194% in tested skin lotions for broader benefits.

Key findings

  1. 01 Demonstrates strong antifungal activity with minimum inhibitory concentrations (MIC) as low as 0.00125% against various fungal isolates.
  2. 02 Effective in inhibiting hyphal growth of specific fungal species (S. parasitica and Aphanomyces spp.) at 0.01%.
  3. 03 Achieves minimum inhibitory concentrations (MIC) against Staphylococcus aureus at 0.003% - 0.005% (30-50 µg/mL).
  4. 04 Shows potent antibacterial effects against oral bacteria such as Streptococcus mutans, Porphyromonas gingivalis, and Streptococcus pneumoniae isolates, with MICs ranging from 0.00003% to 0.0001% (0.3-1.0 µg/mL).
  5. 05 Has been quantified in commercial skin lotions at approximately 0.0194% (194 ± 14 μg/ml), indicating practical formulation stability and presumed efficacy at this level.

Transparency

Not commonly dusted
Min. effective
0.02%

Hinokitiol exhibits significant biological activity at very low concentrations, with minimum inhibitory concentrations (MICs) against various microbes ranging from 0.00003% to 0.01%. It has also been found in a tested skin lotion at approximately 0.0194%. While specific regulatory maximums are unknown globally, concentrations significantly exceeding 0.02% may suggest 'dusting' if not justified by additional efficacy data or specific formulation requirements beyond the established effective ranges.


The Formula

Solubility
Both
Optimal pH 4 – 6.5
0 7 14

Stability

Hinokitiol maintains stability within a pH range of 4 to 6.5. Formulations should avoid temperatures exceeding 40°C. Due to its chelating properties, it can form salts upon contact with metal ions, potentially leading to discoloration in the product.

Conflicts

  • metal ions (can cause coloring and salt formation)

Safety

CIR Status
Not reviewed
Sensitization risk Low

Hinokitiol is classified in Canada as non-persistent, non-bioaccumulative, and non-toxic to aquatic organisms, generally exhibiting low toxicity. However, Japan's Ministry of Health regulates its use and concentration in certain cosmetic categories. The raw chemical is listed as an 'Irritant' by PubChem, though formulated products containing Hinokitiol are typically well-tolerated. Oral LD50 in rats is 500 mg/kg. It is permitted in EWG VERIFIED products, provided specific usage restrictions and warnings are met.


Your Skin

Yes Normal
No Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

Hinokitiol is a highly valuable multi-functional ingredient offering significant antimicrobial, anti-inflammatory, antioxidant, and skin-brightening benefits at low concentrations, making it suitable for a wide range of precision skincare formulations.


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