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HEXACHLOROPHENE.

Avoid / PRESERVATIVE

Hexachlorophene is a potent broad-spectrum antibacterial agent, notably effective against Gram-positive bacteria by disrupting their cellular membranes. Despite its efficacy, its use in skincare and medicine is severely restricted and largely abandoned due to significant neurotoxicity and stringent regulatory warnings.

Antibacterial Antiseptic Preservative

Science

Hexachlorophene exerts its antibacterial action by integrating into and disrupting bacterial cytoplasmic membranes. This process increases membrane permeability, leading to the leakage of essential cellular contents and metabolites, ultimately causing bacterial cell death. It is predominantly active against Gram-positive bacteria such as Staphylococcus aureus and Streptococcus species. While lower concentrations may interfere with electron transport and inhibit membrane-bound enzymes, higher concentrations induce membrane rupture.


Research

High confidence
Effective range 0.00005–3%
Optimal

0.1%

Key findings

  1. 01 In vitro studies indicate a minimum inhibitory concentration (MIC) ranging from 0.5 to 4 µg/mL against Staphylococcus aureus, demonstrating potent antibacterial activity.
  2. 02 Preclinical animal studies (rat skin colonization models) showed an effective reduction of skin bacterial counts by over 90%.
  3. 03 Historically, 3% hexachlorophene emulsions were used in surgical scrubs, but this led to detectable blood levels in subjects and subsequent neurotoxicity concerns.

Transparency

Commonly dusted
Red flag below
0.1%

Hexachlorophene is classified by the FDA as 'NOT generally recognized as safe and effective' for use as an antiseptic handwash, meaning any over-the-counter product making such claims is considered 'dusted.' For cosmetic use, its concentration is stringently limited to a maximum of 0.1% exclusively as a preservative, only when no other equally effective alternative is available, and it must not be applied to mucous membranes. Any cosmetic product exceeding 0.1% or making unsupported claims would represent a significant regulatory red flag.


The Formula

Solubility
Oil
Optimal pH 5 – 6
0 7 14

Stability

Prolonged direct exposure to strong light may induce brownish surface discoloration without impacting its antibacterial or detergent properties. It is advisable to avoid dispensing or storing hexachlorophene in containers with ordinary metal parts due to potential discoloration or metal oxidation.

Conflicts

  • Strong oxidizers
  • Alkalis and alkaline earths (forms salts)
  • Other topical antiseptics or disinfectants (may enhance skin irritation or cumulative toxicity)
  • Products containing alcohol or astringent compounds (can exacerbate skin dryness or remove antibacterial residue)
  • Neurotoxic agents (could heighten neurotoxic side effects)

Safety

CIR Status
Safe with restrictions
Max tested
0.1%
Pregnancy
Caution
Sensitization risk High

The FDA has issued explicit warnings against the routine use of hexachlorophene, particularly for bathing infants, due to well-documented neurotoxicity. Its application in cosmetics is highly restricted to a maximum concentration of 0.1% as a preservative, only when no other preservative has demonstrated comparable effectiveness, and it is strictly prohibited from use on mucous membranes. Prescription drug products containing 3% hexachlorophene have been largely phased out in modern clinical practice due to these substantial safety concerns.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Despite potent antibacterial efficacy, hexachlorophene is unequivocally unsuitable for modern precision skincare formulations due to severe regulatory restrictions, documented neurotoxicity, and a high risk of irritation.


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