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FUMARIC ACID.

Valuable CAS 110-17-8 / BUFFERING

Fumaric Acid, a naturally occurring dicarboxylic acid, acts primarily as a precise pH adjuster and buffering agent in skincare formulations. At elevated concentrations, it contributes to mild exfoliation by dissolving dead skin cell bonds, promoting a smoother and clearer skin texture.

pH Adjuster Buffering Exfoliation (mild) Cell Renewal (indirect)

Science

As a fruit acid, Fumaric Acid primarily functions by stabilizing the pH of cosmetic products, acting as an effective buffering agent to maintain optimal formulation integrity. When present in higher concentrations, it works on the stratum corneum by weakening the bonds between accumulated dead skin cells, thereby facilitating their natural shedding. This process indirectly stimulates the skin's innate cell renewal mechanisms, which can lead to enhanced skin elasticity and a visibly refined, fresher complexion.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH N/A
0 7 14

Stability

Fumaric Acid is chemically stable at room temperature but requires dry and airtight storage for optimal preservation. Its aqueous solution has a pH of approximately 2.1, with pKa values measured at 3.03 and 4.44 (at 15-25 °C). Technical grade Fumaric Acid typically maintains a shelf life of 1825 days.

Conflicts

  • bases
  • reducing agents
  • strong oxidizing agents
  • amines

Safety

CIR Status
Safe as used
Sensitization risk Low

The Cosmetic Ingredient Review (CIR) Expert Panel has concluded that Fumaric Acid, along with its salts and esters, is safe for use in cosmetic and personal care products. Fumaric Acid is a normal constituent found naturally within the human body. It is crucial to distinguish it from smaller fumarate esters (e.g., dimethyl fumarate), which are not typically used in cosmetics and have been identified as potent dermal sensitizers. In contrast, larger fumarate esters approved for cosmetic use, such as Diisostearyl Fumarate, have demonstrated no sensitization potential.


Your Skin

No Normal
No Dry
Yes Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Valuable

Fumaric Acid is a valuable ingredient primarily recognized for its precise pH adjusting and buffering capabilities, with additional mild exfoliating benefits when used at higher concentrations, and demonstrates a low sensitization risk.


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