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FORMIC ACID.

Optional CAS 64-18-6 / FRAGRANCE, pH ADJUSTERS, PRESERVATIVE

Formic acid is a short-chain carboxylic acid utilized in cosmetic formulations primarily as a pH adjuster and preservative. It supports product stability by balancing acidity and inhibiting microbial proliferation, thus extending shelf life and ensuring formula integrity.

pH Adjuster Preservative Fragrance Antibacterial Antifungal

Science

This ingredient functions by modulating the pH of cosmetic products to achieve optimal stability and compatibility with the skin's acidic mantle. Its preservative action involves creating an environment unfavorable for microorganism growth, and it may also provide antibacterial and antifungal benefits. However, at elevated concentrations, its acidic nature can induce a stinging sensation and even lead to corrosive effects on the skin.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 3 – 6
0 7 14

Stability

Formic acid is readily water-miscible. In cosmetic applications, it is typically neutralized to formate salts, which helps to mitigate potential safety concerns. Formulations are generally targeted to a pH range of 4 to 6 to align with the skin's natural pH, though some compositions with organic acid buffer systems may maintain a pH between 3 and 5.


Safety

CIR Status
Safe with restrictions
Max tested
0.2%
Sensitization risk Unknown

The Cosmetic Ingredient Review (CIR) Expert Panel concluded that formic acid is safe for use in cosmetics under current practices, provided formulations are non-irritating. A previous CIR report established a limit of 64 ppm for free formic acid when used as a pH adjuster. Formic acid is generally used at concentrations up to 0.2% (or 0.34% for sodium formate), with lower concentrations in leave-on products (e.g., 0.2% in aerosol hair sprays) and usage in rinse-off products minimizing irritation concerns. The FDA recognizes formic acid as generally recognized as safe (GRAS) for food additive uses. In the European Union, it is approved as a preservative at a maximum concentration of 0.5% (expressed as acid).


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Optional

Formic acid is an optional ingredient, primarily valued for its functional roles in pH adjustment and preservation; however, its high irritancy potential necessitates precise formulation and very low concentrations, offering no direct skin-benefiting efficacy for precision skincare.


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