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FERRIC AMMONIUM CITRATE.

Questionable CAS 1185-57-5 / HAIR DYEING

Ferric Ammonium Citrate primarily functions as a coloring agent in cosmetic formulations, imparting various hues. It also exhibits secondary properties as an antioxidant to stabilize formulations and a conditioning agent.

Coloring Agent Antioxidant Conditioning Agent

Science

This iron compound is primarily valued for its coloring capabilities in cosmetics. Within the formulation, it may act as an antioxidant, mitigating the oxidation of other ingredients and thereby enhancing product shelf life. While it can also serve as a conditioning agent, its ferric ions are known to participate in redox reactions. Notably, in cellular environments, Ferric Ammonium Citrate has been observed to accelerate the Fenton reaction, a process that generates reactive oxygen species (ROS).


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Water
Optimal pH 5 – 8
0 7 14

Stability

A 5% aqueous solution of Ferric Ammonium Citrate maintains a neutral pH between 5.0 and 8.0. It is stable under typical conditions but demonstrates photosensitivity, undergoing decomposition and reduction to a ferrous salt upon light exposure. The green variant is generally more light-sensitive than the brown, and the compound is hygroscopic.


Safety

CIR Status
Safe with restrictions
Max tested
3%
Sensitization risk Unknown

The Cosmetic Ingredient Review (CIR) Expert Panel has deferred its full evaluation of Ferric Ammonium Citrate, referencing FDA assessments of related iron ferrocyanide color additives. The FDA permanently permits Ferric Ammonium Citrate without certification for coloring surgical sutures, specifically plain or chromic catgut, at concentrations not exceeding 3%. It also holds approval as a food additive. However, related iron ferrocyanides, while deemed safe by the FDA for external cosmetic applications, including the eye area, are explicitly prohibited for use on the lips. The potential for Ferric Ammonium Citrate to accelerate ROS generation in cellular contexts warrants careful consideration for its application in precision skincare.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Questionable

While serving as an effective cosmetic colorant and formulation stabilizer, the lack of specific skin efficacy data and the reported potential for reactive oxygen species generation make its direct benefit in precision skincare questionable.


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