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ETHYLHEXYL METHACRYLATE.

Avoid CAS 688-84-6 / FILM FORMING

Ethylhexyl Methacrylate is a synthetic monofunctional methacrylate ester monomer, extensively utilized in polymer systems for its capacity to impart flexibility, toughness, and weathering resistance. In cosmetic formulations, its primary role is as a film-forming agent, creating hydrophobic properties and enhancing the cohesive strength of product matrices.

Film-forming Adhesive

Science

This compound functions by polymerizing to form homopolymers or copolymers, which then create a thin, cohesive film on surfaces. In topical applications, this film contributes to a hydrophobic barrier, improving product adherence and resilience, while also offering flexible and conformable properties.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH N/A
0 7 14

Stability

Ethylhexyl Methacrylate exhibits high hydrolytic stability, showing negligible degradation at neutral pH (7.4) and a low hydrolysis rate under mildly alkaline conditions (pH 10). Acid-catalyzed hydrolysis is generally slower. However, it is sensitive to heat and light, which can induce polymerization. To prevent this, storage must always be under air (oxygen is vital for stabilizer function) and at temperatures not exceeding 35 °C.

Conflicts

  • strong acids
  • strong oxidizing agents
  • strong bases
  • heat
  • oxygen-free atmosphere
  • free radicals
  • peroxides
  • inhibitor depletion
  • light

Safety

CIR Status
Safe with restrictions
Sensitization risk High

The Cosmetic Ingredient Review (CIR) Expert Panel has deemed Ethylhexyl Methacrylate safe for use in nail enhancement products, provided that direct skin contact is strictly avoided due to its recognized sensitizing potential. This determination was reconfirmed in 2021-2022. There is no established maximum concentration for direct skin application in cosmetics, as contact is explicitly advised against. The FDA permits its use as an indirect food additive in coatings.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy Unknown
Comedogenicity Unknown

Our Assessment

Avoid

Due to its high sensitizing potential and regulatory advice to avoid skin contact, Ethylhexyl Methacrylate is not recommended for direct application in precision skincare formulations.


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