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DIHYDROXYACETONE.

Valuable CAS 96-26-4 / HAIR DYEING, SKIN CONDITIONING - MISCELLANEOUS, TANNING

Dihydroxyacetone (DHA) is a key active ingredient in sunless tanning products, producing a temporary tan. It is also found in some cosmetic bases and used as an adjunctive treatment for specific skin conditions.

reducing skin conditioning tanning

Science

DHA reacts with amine functions on amino acids in the stratum corneum via a Maillard reaction, forming brown melanoidin pigments. This non-enzymatic browning mimics melanin, providing a tanned appearance that fades with skin cell turnover.


Research

High confidence
Effective range 4–8%
Optimal

6%

Key findings

  1. 01 DermNet, In search of the perfect tan: Chemical activity, biological effects, business considerations, and consumer implications of dihydroxyacetone sunless tanning products
  2. 02 Dihydroxyacetone: An Updated Insight into an Important Bioproduct - PMC
  3. 03 Typology
  4. 04 DropBio

Transparency

Not commonly dusted

Dihydroxyacetone is an active ingredient in self-tanning products, requiring specific concentrations to achieve its intended effect, and is not typically used in trace or 'dusted' amounts.


The Formula

Solubility
Water
Optimal pH 4 – 5
0 7 14

Stability

DHA is optimally stable at pH 4-5, with solutions stable between pH 4-6; degradation occurs in more basic solutions. It is heat-instable and should be added during the final cool-down phase of formulation, requiring cool, dry storage.

Conflicts

  • Primary and secondary amines
  • Other nitrogen-containing compounds
  • Oxidizing agents
  • Metals (iron, copper, manganese, titanium)
  • Alpha-hydroxy acids
  • Titanium dioxide
  • Zinc oxide
  • Iron oxide pigments
  • Certain perfumes
  • EDTA

Safety

CIR Status
Deferred evaluation
Max tested
15%
Pregnancy
Caution
Sensitization risk Moderate

CIR deferred evaluation as FDA assessed safety; approved for external use up to 15%. FDA warns against inhalation/ingestion. Studies suggest DHA may generate free radicals, potentially damaging skin components and limiting Vitamin D. Caution advised for pulmonary disease, rosacea, and dermatitis; generally avoided in pregnancy.


Your Skin

Yes Normal
No Dry
Yes Oily
No Sensitive
Irritancy Moderate
Comedogenicity Unknown

Our Assessment

Valuable

Dihydroxyacetone is a valuable active ingredient for achieving a temporary tanned complexion through a proven Maillard reaction, but requires careful formulation and use due to potential safety concerns.


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