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DIETHANOLAMINE BISULFATE.

Valuable CAS 59219-56-6 / BUFFERING

An electrolytic salt derived from diethanolamine and sulfuric acid, primarily utilized as a high-precision buffering agent to stabilize cosmetic formulations. It ensures product integrity by maintaining a skin-compatible pH range, preventing acidic degradation of other active ingredients.

buffering agent pH adjuster surfactant

Science

Upon introduction to an aqueous system, the molecule dissociates into diethanolammonium cations and bisulfate anions. These ions act as chemical anchors that neutralize acidity and resist pH fluctuations, ensuring the formulation remains within the optimal physiological window for skin application.


Research

High confidence
Effective range 0.1–5%
Optimal

2.5%

Key findings

  1. 01 Ocular assessments using MTT assays and Draize protocols demonstrate that a 10% concentration is classified as a non-to-minimal irritant.
  2. 02 Dermal penetration research indicates approximately 30% skin accumulation over a 72-hour period when applied in concentrated (37%) formats, highlighting the importance of regulated dosage.

Transparency

Not commonly dusted
Min. effective
0.5%
Red flag below
0.1%

As a functional stabilizer rather than an active treatment, 'dusting' is less relevant here; however, concentrations below 0.1% may fail to provide adequate pH buffering for complex formulas.


The Formula

Solubility
Water
Optimal pH 6 – 9
0 7 14

Stability

Highly hygroscopic and stable in water-based environments. It is most effective when stabilizing formulations near its pKa of 8.88.

Synergies

  • Water-soluble surfactants
  • Chelating agents

Conflicts

  • N-nitrosating agents (e.g., Sodium Nitrite)
  • Strong oxidizing agents
  • Formaldehyde donors

Safety

CIR Status
Safe with restrictions
Max tested
5%
Pregnancy
Safe
Sensitization risk Low

Must not be used in the presence of nitrosating agents to prevent the formation of carcinogenic nitrosamines. Total ethanolamine content must remain below 5% for leave-on products.


Your Skin

Yes Normal
Yes Dry
Yes Oily
No Sensitive
Irritancy Low
Comedogenicity Unknown

Our Assessment

Valuable

A robust and reliable pH stabilizer for aqueous formulas, though it requires strict avoidance of nitrosating contaminants.


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