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CI 77491.

Valuable CAS 1309-37-1 / 1317-61-9 / 1345-27-3 / 52357-70-7 / 1345-25-1 / COLORANT

CI 77491, commonly known as red iron oxide, is a stable mineral pigment primarily utilized for its cosmetic coloring properties, imparting reddish or pinkish hues to formulations. Beyond its aesthetic function, this ingredient offers significant protective benefits against visible and blue light-induced skin damage and pigmentation.

colorant visible light protection blue light protection skin tone evening

Science

Functioning as both a cosmetic pigment and a photoprotective agent, CI 77491 imparts red tones while actively safeguarding the skin. It attenuates high-energy visible light, specifically blue light within the 400 nm to 500 nm range, through a combination of absorption and reflection. This action helps to mitigate blue light-induced skin aging and hyperpigmentation, with an additional mild protective effect against UV radiation. Its inherent reflective properties also contribute to visually diffusing imperfections and promoting a more even skin tone.


Research

High confidence
Effective range N/A
Optimal

N/A

Key findings

  1. 01 Clinical studies demonstrate that formulations containing iron oxides, including CI 77491, provide significant protection against visible light-induced pigmentation in individuals with Fitzpatrick IV skin types. These formulations surpassed non-tinted mineral SPF 50+ sunscreens in preventing new pigmentation triggered by sunlight exposure and aiding in the masking of existing discoloration.
  2. 02 Research indicates that CI 77491 (red iron oxide) enhances protection against certain wavelengths of high-energy visible light. It specifically attenuates visible blue light, approximately between 400 nm and 500 nm, through both absorption and reflection mechanisms, thereby offering enhanced protection against skin damage.

Transparency

Not commonly dusted

The Formula

Solubility
Oil
Optimal pH 6 – 7
0 7 14

Stability

CI 77491 exhibits robust stability, demonstrating resistance to degradation from light, heat, acids, and alkalis. Optimal stability is observed within a pH range of 6.0 to 7.0. While it is insoluble in water and most organic solvents, it disperses effectively in fats and concentrated mineral acids, and is considered miscible in both water and oils for cosmetic formulation purposes.


Safety

CIR Status
Safe as used
Sensitization risk Low

The Expert Panel for Cosmetic Ingredient Safety (CIR) defers to FDA assessment, deeming CI 77491 safe for use. The FDA approves it as a color additive, exempt from batch certification, for use in cosmetics—including the eye area—in quantities consistent with good manufacturing practices. Similarly, the EU's Scientific Committee on Consumer Safety (SCCS) permits its use as a colorant without restriction, provided purity requirements are met. It is considered non-allergenic and non-toxic, with strict regulatory purity standards enforced to limit potential contaminants. Typical application concentrations vary by product type: 0.2–10.0% in foundations, concealers, and BB/CC creams; 0.1–8.0% in blush, bronzer, and contour products; 0.5–20.0% in eyeshadows; and 0.05–5.0% in lipsticks and lip products.


Your Skin

Yes Normal
Yes Dry
Yes Oily
Yes Sensitive
Irritancy Low
Comedogenicity Low

Our Assessment

Valuable

CI 77491 is a valuable ingredient, not only imparting cosmetic color but also providing proven protection against visible and blue light-induced hyperpigmentation and skin damage, making it suitable for all skin types.


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