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CHLOROSALICYLIC ACID.

Avoid CAS 321-14-2 / SKIN CONDITIONING

Chlorosalicylic Acid is a halogenated derivative structurally related to salicylic acid, which implies potential benefits such as exfoliation and addressing hyperpigmentation. However, comprehensive safety data for its cosmetic application is lacking, and its various isomers exhibit significant cautionary classifications.

Exfoliant (potential) Anti-Acne (potential, via pore unclogging and sebum reduction) Antimicrobial (certain isomers) Hyperpigmentation reduction (potential, via tyrosinase inhibition)

Science

Functionally analogous to salicylic acid, Chlorosalicylic Acid is postulated to promote skin exfoliation by softening keratin, thereby aiding in the detachment of dead skin cells and preventing pore blockages. It may also contribute to reduced sebum secretion and improved hyperpigmentation. Specific isomers, such as 4-Chlorosalicylic Acid, are noted for potent antimicrobial activity and the ability to inhibit monophenolase and diphenolase, enzymes involved in melanin synthesis.


Research

Low confidence
Effective range N/A
Optimal

N/A


Transparency

Not commonly dusted

There is no available information to indicate that Chlorosalicylic Acid is commonly dusted in cosmetic applications, nor are there thresholds for dusting behavior.


The Formula

Solubility
Unknown
Optimal pH N/A
0 7 14

Stability

Solubility varies significantly among isomers; 3-Chlorosalicylic acid is water-soluble, while 4-Chlorosalicylic acid is water-insoluble but soluble in DMSO and ethanol. For optimal stability, the compound should be stored in a cool, dry, well-ventilated environment, away from incompatible substances, with containers securely sealed.

Conflicts

  • Strong oxidizing agents
  • Strong bases
  • Active metals

Safety

CIR Status
Not reviewed
Sensitization risk High

Safety information for 3-Chlorosalicylic acid is reportedly 'not available' from one source. General GHS classifications for various isomers (3-, 4-, and 5-Chlorosalicylic acid) indicate severe hazards, including toxicity if swallowed, causing skin irritation, serious eye irritation, and potential respiratory irritation. The oral LD50 in rats for 5-Chlorosalicylic acid is quantified at 250 mg/kg. Regulatory bodies, such as the New Zealand EPA, note that 3-Chlorosalicylic acid and 4-Chlorosalicylic acid lack individual approval for use as standalone chemicals but may be components in group-standard products. Critically, no specific cosmetic safety assessments by CIR, SCCS, or FDA were identified for Chlorosalicylic Acid or its isomers, only for Salicylic Acid.


Your Skin

No Normal
No Dry
No Oily
No Sensitive
Irritancy High
Comedogenicity Unknown

Our Assessment

Avoid

Given the explicit GHS hazard classifications indicating skin and eye irritation, general toxicity, and the absence of specific cosmetic safety assessments by major regulatory bodies, Chlorosalicylic Acid is deemed unsuitable for precision skincare formulations.


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